Synthesis, Structure and Characterization of Manganese(Ⅱ) Coordination Polymer with Camphoric Acid and 1,10-Phenanthroline

Abstract

Abstract: A novel coordination polymer, Mn(H₂O)(CA)(Phen)·H₂O(CA=camphoric acid, Phen=1,10-phenanthroline), was synthesized and its crystal structure was determined by single crystal X-ray diffraction. Six-coordinated Mn(Ⅱ) atoms are linked with carboxyl groups from camphoric acid ligands to form infinite one-dimensional chains. These chains are packed by means of hydrogen bonding and π-π stacking, forming a three-dimensional structure. IR, thermogravimetric analysis and magnetic susceptibility data for Mn(H₂O)(CA)(Phen)·H₂O are given.

Key words: Coordination polymer, Camphoric acid, 1,10-Phenanroline, Magnetic property, Crystal structure

HOU Ying, SHI Zhan, YANG Ming, LI Guang-hua, FENG Shou-hua. Synthesis, Structure and Characterization of Manganese(Ⅱ) Coordination Polymer with Camphoric Acid and 1,10-Phenanthroline[J]. Chemical Research in Chinese Universities, 2005, 21(4): 406-410.

References

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