Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties

doi:10.1007/s40242-019-9015-7

Abstract

Abstract: We synthesized three new Ni(Ⅱ) coordination polymers[Ni(L)(HIP)(H₂O)₂]·H₂O(CP1),[Ni(L)(NIP)]·2H₂O(CP2) and[Ni(L)(NDC)(H₂O)₂](CP3)[L=N,N'-bis(pyridine-3-yl)thiophene-2,5-dicarboxamide, H₂HIP=5-hydroxyisophthalic acid, H₂NIP=5-nitroisophthalic acid, H₂NDC=2,6-naphthalenedicarboxylic acid] by hydrothermal method, which were characterized by means of infrared spectra(IR), TG analyses, PXRD and single-crystal X-ray diffraction. The CP1 is a 1D tubular structure based on[Ni-HIP]₂ loops and pairs of L ligands. CP2 is a 2D 3,5-connected architecture, which consists of Ni-L linear chains and (Ni-NIP)₂ double chains. CP3 is a 2D network, which features 4-connected topology. Solid-state luminescent behaviours of CP1-CP3 were investigated. The CP1 can detect Fe³⁺ ions through luminescence quenching. The electrochemical properties of CP1 buk-modified carbon paste electrode(CP1-CPE) has also been investigated, which has bifunctional electrocatalytic activity for oxidation of ascorbic acid and reduction of NO₂^-.

Key words: Carboxylate-induced, Coordination polymer, Fluorescent recognition, Bifunctional electrocatalysis

LU Xue, LIU Guocheng, WANG Xiang, LIN Hongyan, WANG Xiuli. Carboxylate-induced Various Structures of Ni(Ⅱ) Complexes with Fluorescence Sensing and Bifunctional Electrochemical Properties[J]. Chemical Research in Chinese Universities, 2019, 35(4): 549-555.

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