Multi-functional Photoelectric Sensor Based on a Three-fold Interpenetrated Cd(II) Coordination Polymer for Sensitively Detecting Different Ions

doi:10.1007/s40242-022-1445-y

Abstract

Abstract: Athree-fold interpenetrated cadmium coordination polymer[Cd₃(BTC)₂(H₂O)₉]·2H₂O(CP 1)(H₃BTC=1,3,5-benzenetricar-boxylic acid) was selected and synthesized to investigate its photoelectric properties. CP 1 showed excellent sensitivity for Cr₂O₇^2- and Fe³⁺, low limit of detection(LOD:0.39 µmol/L for Cr₂O₇^2- and 1.72 µmol/L for Fe³⁺) and stability as electrochemical sensor. More importantly, fluorescence sensing studies indicated that CP 1 exhibits sensing activity for Fe³⁺, Fe²⁺, and MnO₄^- with good cyclic stability and selectivity. Low LOD and high-sensitivity capability of CP 1 make it a potential multifunctional photoelectric sensor.

Key words: Coordination polymer, Photoelectric sensor, Electrochemistry sensing, Fluorescence sensing, Cr₂O₇^2- and MnO₄^-

WANG Yue, WANG Jinling, MA Jianxin, ZHANG Yue, XU Na, WANG Xiuli. Multi-functional Photoelectric Sensor Based on a Three-fold Interpenetrated Cd(II) Coordination Polymer for Sensitively Detecting Different Ions[J]. Chemical Research in Chinese Universities, 2022, 38(4): 1105-1110.

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