Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)3]·ZTO·6H2O and[Cu(phen)3]·ZTO·6H2O

doi:10.1007/s40242-018-8051-z

Abstract

Abstract: [Zn(phen)₃]·ZTO·6H₂O(1) and[Cu(phen)₃]·ZTO·6H₂O(2) were synthesized by the reaction of Zn(NO₃)₂·6H₂O/Cu(NO₃)₂·3H₂O with 4,4-azo-1H-1,2,4-triazol-5-one(ZTO) and 1,10-phenanthroline(phen). The two compounds were characterized by elemental analysis and IR spectrum analysis, respectively. Compound 1 was also characterized by single crystal X-ray diffraction analysis. For compound 1, the coordination geometry around the Zn²⁺ is a distorted octahedron, with the bite angles of 76.7(3)°-77.6(4)° for all three phen ligands. Moreover, the thermal behaviors and thermal decomposition kinetics were studied and analyzed. Besides, thermal stability and safety parameters(T_SADT, T_b) are 164.7 and 166.4℃ for compound 1, and 149.6 and 150.8℃ for compound 2, respectively.

Key words: Azo-triazole, [Zn(phen)₃]·ZTO·, 6H₂O, [Cu(phen)₃]·ZTO·, 6H₂O, Crystal structure, Thermal behavior

DING Zimei, CAO Wenli, ZHENG Hui, HUANG Jie, XU Kangzhen, SONG Jirong. Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O[J]. Chemical Research in Chinese Universities, 2018, 34(6): 1009-1013.

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Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O

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