Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties

doi:10.1007/s40242-020-9079-4

Chemical Research in Chinese Universities ›› 2020, Vol. 36 ›› Issue (1): 74-80.doi: 10.1007/s40242-020-9079-4

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Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties

QIAN Binbin^1,3, CHANG Ze^1,3,4, BU Xian-He^1,2,3

1. School of Materials Science and Engineering, National Institute for Advanced Materials, Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300350, P. R. China;
2. State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, P. R. China;
3. Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), Tianjin 300072, P. R. China;
4. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure, Chinese Academy of Sciences, Fuzhou 350002, P. R. China

Received:2019-12-02 Revised:2019-12-30 Online:2020-02-01 Published:2020-01-02
Contact: CHANG Ze E-mail:changze@nankai.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21531005, 91856124, 21671112, and 21875115).

Abstract

Abstract: By employing an electron-rich tricarboxytriphenyl amine as donor ligand and electron-deficient 2,4,6-tris(pyridin-4-yl)-1,3,5-triazine as acceptor ligand to assemble with Zn²⁺ ions, three new coordination polymers were successfully synthesized and characterized systematically. Three compounds with different structures were obtained by regulating the reaction solvent, and the effect of the reaction solvent on the synthesis of crystals was explored. Furthermore, the photophysical properties of the compounds were investigated.

Key words: Coordination polymer, Donor-acceptor interaction, Tricarboxytriphenyl amine, 2,4,6-Tris(pyridin-4-yl)-1,3,5-triazine

QIAN Binbin, CHANG Ze, BU Xian-He. Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties[J]. Chemical Research in Chinese Universities, 2020, 36(1): 74-80.

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Zinc-coordination Polymers Based on a Donor-acceptor Mix-ligand System: Syntheses, Crystal Structures and Photophysical Properties

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