Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance

doi:10.1007/s40242-019-9138-x

Abstract

Abstract: The structure of 4-amino-3-(5-tetrazolate)-furazan(HAFT) was characterized by single crystal X-ray diffraction. The thermal decomposition process of HAFT was investigated by MS-FTIR-DSC-TG coupling technique. The result shows that the exothermic process occurs from 278.7-350℃, with a peak temperature of 324.7℃. The thermal decomposition gaseous products of HAFT are NO₂, CO₂, HCN, CO, NH₃ and H₂O. The detonation velocity and detonation pressure of HAFT were calculated by the nitrogen equivalent equation. The detonation velocity of HAFT is 7727.46 m/s, which is higher than that of TNT(7178 m/s). The detonation pressure of HAFT(25.27 GPa) is satisfactory. The sensitivity tests reveal HAFT possesses excellent insensitivities to impact and friction.

Key words: 3-Amino-4-(1H-tetrazol-5-yl)-furazan, Crystal structure, Thermal behavior, Gas product, Energetic performance

MA Xiao, WANG Xiaohong, SHANG Fan, DING Zimei, HANG Xiaojing, HUANG Jie. Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance[J]. Chemical Research in Chinese Universities, 2019, 35(5): 848-853.

References

[1] Gao H., Shreeve J. M., Chem. Rev., 2011, 111, 7377
[2] Fischer D., Gottfried J. L., Klapötke T. M., Karaghiosoff K., Stierstorfer J., Witkowski T. G., Angew. Chem. Int. Ed., 2016, 55, 16132
[3] Steinhauser G., Klapötke T. M., Angew. Chem. Int. Ed., 2008, 47, 3330
[4] Yu Q., Imler G. H., Parrish D. A., Shreeve J. M., Chem. Eur. J., 2017, 23, 17682
[5] Ma Q., Gu H., Huang J. L., Liu D. B., Li J. S., Fan G. J., Propellants Explos. Pyrotech., 2018, 43, 90
[6] Su Q., Wang X. J., Shu Q. H., Jin S. H., Chen S. S., Li L. J., J. Heterocycl. Chem., 2018, 55, 481
[7] Qu Y. Y., Wei Z. X., Kang L., Xie F., Zhang H. D., Yue P., Z. Anorg. Allg. Chem., 2017, 643, 742
[8] Liang L. X., Huang H. F., Wang K., Bian C. M., Song J. H., Ling L. M., Zhao F. Q., Zhou Z. M., J. Mater. Chem., 2012, 22, 21954
[9] Liang L., Wang K., Bian C., Ling L., Zhou Z. M., Chem. Eur. J., 2013, 19, 14902
[10] Wang R. H., Guo Y., Zeng Z., Twamley B., Shreeve J. M., Chem. Eur. J., 2009, 15, 2625
[11] Wu B. D., Li X. Y., Liang J., Geng X. H., Huang H. S., Huang H., Wang J. Y., Hu W. H., Polyhedron, 2018, 139, 148
[12] Wu B. D., Liang J., Wang J. Y., An C. W., Main Group Chem., 2017, 16, 67
[13] Wang J. Y., Liang J., Wu B. D., An C. W., Main Group Chem., 2016, 15, 325
[14] Sheldrick G. M., SHELXS-97, Program for X-ray Crystal Structure Determination, University of Göttingen, Göttingen, 1997
[15] Sheldrick G. M., SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Göttingen, 1997
[16] Fischer N., Klapötke T. M., Reymann M., Stierstorfer J., Eur. J. Inorg. Chem., 2013, 2013, 2167
[17] Yin P., Zhang J., He C., J. Mater. Chem. A., 2014, 9, 3200
[18] Lide D. R., Standard Thermodynamic Properties of Chemical Substances, CRC Handbook of Chemistry and Physics, 87th Ed., Taylor and Francis, Boca Raton, 2007
[19] Xu J. G., Wang S. H., Zhang M. J., Sun C., Xiao Y., Li R., Zheng F. K., Guo G. C., Huang J. S., ACS Omega., 2017, 2, 346
[20] Qiu H., Stepanov V., di Stasio A. R., Chou T. M., Lee W. Y., J. Hazard. Mater., 2011, 185, 489
[21] Guo Y. X., Zhang H. S., Explos. Shock Waves, 1983, 3, 56
[22] Wang Y., Zhang J. C., Su H., Li S. H., Zhang S. W., Pang S. P., J. Phys. Chem. A., 2014, 118, 4575
[23] Klapotke T. M., Martin F. A., Mayr N. T., Stierstorfer J. Z., Z Anorg. Allg. Chem., 2010, 636, 2555
[24] Zhang J., Shreeve J. M., J. Am. Chem. Soc., 2014, 136, 4437
[25] Mehta N., Oyler K., Cheng G., Shah A., Marin J., Yee K., Z. Anorg. Allg. Chem., 2014, 640, 1309
[26] Talawar M. B., Sivabalan R., Mukundan T., Muthurajan H., Sikder A. K., Gandhe B. R., Rao A. S., J. Hazard. Mater., 2009, 161, 589
[27] Yang Z., Liu Y., Liu D., Yan L., Chen J., J. Hazard. Mater., 2010, 177, 938
[28] Yang L., Wu B. D., Zhang T. L., Liu Z. H., Zhang J. G., Propellants Explos. Pyrotech., 2010, 35, 521
[29] Wu B. D., Yang L., Wang S. W., Zhang T. L., Zhang J. G., Zhou Z. N., Yu K. B., Z. Anorg. Allg. Chem., 2011, 637, 450
[30] Liu Z. H., Zhang T. H., Zhang J. G., Wang S. Z., J. Hazard. Mater., 2008, 154, 832
[31] Zhang X. G., Study on Synthesis and Thermal Decomposition of High-nitrogen Compounds and Their Energetic Materials, School of National University of Defense Technology, Beijing, 2005