Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu2Pr2, Cu2Eu2 and Cu4Tb2

doi:10.1007/s40242-019-9058-9

Chemical Research in Chinese Universities ›› 2019, Vol. 35 ›› Issue (4): 693-699.doi: 10.1007/s40242-019-9058-9

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Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂

ZHONG Liangxuan¹, LIU Mingyue¹, ZHANG Bowei¹, SUN Yaqiu^1,2, XU Yanyan¹

1. Tianjin Key Laboratory of Structure and Performance for Functional Molecule, College of Chemistry, Tianjin Normal University, Tianjin 300387, P. R. China;
2. Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education, Nankai University, Tianjin 300071, P. R. China

Received:2019-02-28 Revised:2019-06-04 Online:2019-08-01 Published:2019-08-01
Contact: SUN Yaqiu, XU Yanyan E-mail:hxxysyq@tjnu.edu.cn;hxxyxyy@tjnu.edu.cn
Supported by:
Supported by the Program for Innovative Research Team in University of Tianjin, China(No.TD12-5038), and the "111 Project" of Nankai University, China(No.B12015).

Abstract

Abstract: Three new 3d-4f heterometallic coordination polymers(CPs), namely,[Pr₂(CuL)₂(nipt)₃(H₂O)]×2H₂O (Cu₂Pr₂, 1),[Eu₂(CuL)₂(nipt)₃(H₂O)]×2H₂O(Cu₂Eu₂, 2) and[Tb₂(CuL)₄(nipt)₃]·8.3H₂O(Cu₄Tb₂, 3)(CuL, H₂L=2,3-dioxo-5,6,14,15-dibenzo-1,4,8,12-tetraazacyclo-pentadeca-7,13-dien; nipt^2‒=5-nitroisophthalate) were obtained by a solvothermal method and structurally characterized by single-crystal X-ray diffraction analyses, elemental analyses, Fourier transform infrared spectra and ultraviolet visible absorption spectra. In Cu₂Pr₂ and Cu₂Eu₂, m₃-bridged and m₅-bridged nipt^2‒ ligands alternately linked three Ln³⁺ and five metal ions(three Ln³⁺ and two Cu²⁺ ions) to generate a 2D heterometallic framework with 3,3,4,5-connected (3.4.5)(3².4².5.6³.7²)(4².6³.8)(4².6) topology. In Cu₄Tb₂, m₂-bridged and m₄-bridged nipt^2- ligands alternately connected two Tb³⁺ and four metal ions(two Tb³⁺ and two Cu²⁺ ions) by carboxylating into a corrugated heterometallic 2D layer with 3-connected (6³) topology. The magnetic properties of Cu₂Pr₂ and Cu₂Eu₂ were also discussed, the results show that both CPs have a weak antimagnetic interaction. Moreover, the near-infrared luminescence properties of Cu₂Pr₂ and Cu₂Eu₂ were also studied.

Key words: Heterometallic coordination polymer, Crystal structure, Magnetic property

ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂[J]. Chemical Research in Chinese Universities, 2019, 35(4): 693-699.

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Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂

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