Two Pentavanadate-based Organic-inorganic Materials with Third-order NLO Properties

doi:10.1007/s40242-018-8276-x

Abstract

Abstract: Two isolated organic-inorganic pentavanadate-based hybrids, [H₂N (CH₃)₂]_6.34 [V^V (μ₃-O)₄V^I₄^V O₅ (SO₄)₄]·(SO₄)_0.67·(DMF)· [HN (CH₃)₂]_1.66 (1) and [(HN)₂ (CH₂)₂ (CH₃)₄] [V^V (μ₃-O)₄V₄^IVO₅ (SO₄)₄] [H₂N (CH₃)₂]₃·(DMF)· [HN (CH₃)₂]_0.5 (2) (DMF=N, N-dimethylformamide) have been synthesized under solvothermal conditions and structurally characterized. In compound 1, three adjacent basic units form a triangle type cluster. The symmetric double-layer exists in compound 2. The study of the third-order nonlinear optical (NLO) properties for the two compounds demonstrates that the two-photon absorption (TPA) cross-section σ values of compounds 1 and 2 are 1372 and 1228 GM, respectively, indicating that both compounds may have potential application in optical field.

Key words: Pentavanadate, Third-order nonlinear optical property, Crystal structure

YU Yanzhao, CAO Jiapeng, XU Yan. Two Pentavanadate-based Organic-inorganic Materials with Third-order NLO Properties[J]. Chemical Research in Chinese Universities, 2019, 35(1): 1-4.

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