Bibracchial Lariat Ethers(Ⅰ)——The Synthesis and Crystal Structure of the N,N'-bis(2-Methoxy-1-Naphthylmethyl)-4,13-Diaza-18-Crown-6 Sodium Iodide Complex

Chemical Research in Chinese Universities ›› 1992, Vol. 8 ›› Issue (1): 48-52.

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Bibracchial Lariat Ethers(Ⅰ)——The Synthesis and Crystal Structure of the N,N'-bis(2-Methoxy-1-Naphthylmethyl)-4,13-Diaza-18-Crown-6 Sodium Iodide Complex

Ge Yuhua¹, Wang Defen¹, Hu Hongweng¹, Zhou Zhongyuan², Yu Kaibei²

1. Department of Chemistry, Nanjing University, Nanjing;
2. Chengdu Center of Analysis and Determination, Academic Sinica, Chengdu

Received:1990-11-12 Online:1992-01-24 Published:2011-09-09
Supported by:
Supported by the National Natural Science foundation of China;Laboratory of Magnetic Resonance and Atomic and Molecular Physics,Wuhan Institute of Physics,Academic Soinica,Wuhan

Abstract

Abstract: Diaza Crown ethers are versatile complexing reagents, their complexing abilities are dramatically modified by the electron donating atoms on substituents attached to the nitrogen if they can give a three-dimensional cavity as in cryptates. Hence the synthesis and characterization of bibracchial lariat ethers (BIBLES) have received much attention. In the preparation of new BIBLES, a complex Ⅱ was unexpectedly obtained.

Key words: Bibracchial lariat ether, Diaza-18-crown-6 derivative, Crystal structure, Sodium iodide complex

Ge Yuhua, Wang Defen, Hu Hongweng, Zhou Zhongyuan, Yu Kaibei. Bibracchial Lariat Ethers(Ⅰ)——The Synthesis and Crystal Structure of the N,N'-bis(2-Methoxy-1-Naphthylmethyl)-4,13-Diaza-18-Crown-6 Sodium Iodide Complex[J]. Chemical Research in Chinese Universities, 1992, 8(1): 48-52.

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Bibracchial Lariat Ethers(Ⅰ)——The Synthesis and Crystal Structure of the N,N'-bis(2-Methoxy-1-Naphthylmethyl)-4,13-Diaza-18-Crown-6 Sodium Iodide Complex

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