Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework

doi:10.1007/s40242-017-6293-9

Abstract

Abstract:

A novel polyoxometalate-based hybrid modified by 3d-4d/2-ptz heterometallic organic chains[n-ptz=5-(n-pyridyl)-tetrazolate], Ag₂[Cu(2-ptz)₂][β-Mo₈O₂₆]_0.5·H₂O(1)[2-ptz=5-(2-pyridyl)-tetrazolate], was synthesized under hydrothermal conditions. The 3D framework structure of compound 1 was constructed from 1D novel 3d-4d heterometallic organic chains[CuAg₂(2-ptz)₂]²⁺ as cationic complexes and[β-Mo₈O₂₆]^4- polyoxoanions via Cu-O and Ag-O bonds, in which each[β-Mo₈O₂₆]^4- polyoxoanion was surrounded by six such chains. The electrochemical and photocatalytic properties of compound 1 were investigated.

Key words: Polyoxometalate, Heterometallic organic chain, Crystal structure

WANG Xiang, LIN Lin, LIN Hongyan, LIU Guocheng. Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework[J]. Chemical Research in Chinese Universities, 2017, 33(1): 7-11.

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