Copper(II) Complexes Based on 4'-R-Terpyridine: Synthesis, Structures, and Photocatalytic Properties

doi:10.1007/s40242-017-6319-3

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (1): 1-6.doi: 10.1007/s40242-017-6319-3

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Copper(II) Complexes Based on 4'-R-Terpyridine: Synthesis, Structures, and Photocatalytic Properties

YAN Xia, ZHANG Jianxin

School of Environmental and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China

Received:2016-07-25 Revised:2016-09-22 Online:2017-02-01 Published:2017-01-19
Contact: ZHANG Jianxin,E-mail:zjx1980@126.com E-mail:zjx1980@126.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21302138).

Abstract

Abstract:

Complexes Cu(II)(4'-R-terpyridine)₂(ClO₄)₂[R=2-thienyl(1), 2-(5-bromothienyl)(2), 2-(5-methyl-thienyl)(3) and 2-(5-methoxythienyl)(4)] were synthesized, and their structures were determined by single-crystal X-ray diffraction analyses and were further characterized by high resolution mass spectrometry, infrared spectroscopy(IR), as well as elemental analysis. Single crystal X-ray diffraction analysis shows that Cu(II) ions in the complexes are both six-coordinated with N₆ coordination sphere, displaying distorted octahedral geometries. In addition, the UV-Vis absorption spectra show that the four complexes all exhibit absorption components in both UV and visible light regions. Thus, the photocatalytic activities of the four complexes in the degradation of organic dyes were investigated.

Key words: Copper(II) complex, Single crystal structure, Photocatalytic property

YAN Xia, ZHANG Jianxin. Copper(II) Complexes Based on 4'-R-Terpyridine: Synthesis, Structures, and Photocatalytic Properties[J]. Chemical Research in Chinese Universities, 2017, 33(1): 1-6.

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Copper(II) Complexes Based on 4'-R-Terpyridine: Synthesis, Structures, and Photocatalytic Properties

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