Structure and Fluorescence Property of a Two-fold Interpenetrated Three-dimensional Zn(II) Complex Constructed by Terephthalate and 1,3-Dipyridyl Benzene

doi:10.1007/s40242-015-4433-7

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (3): 328-331.doi: 10.1007/s40242-015-4433-7

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Structure and Fluorescence Property of a Two-fold Interpenetrated Three-dimensional Zn(II) Complex Constructed by Terephthalate and 1,3-Dipyridyl Benzene

XU Jingyao¹, ZHANG Lei¹, SHAO Xueman¹, PAN Chengling^1,2, XU Jiqing²

1. Laboratory of Multiscale Materials and Molecular Catalysis, School of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 232001, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2014-11-17 Revised:2015-01-16 Online:2015-06-01 Published:2015-01-26
Contact: PAN Chengling E-mail:chengling_pan@126.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21201006), the Natural Science Foundation of Anhui Province, China(No.1308085QB34) and the Special Research Fund for the Doctoral Program of Higher Education, China (No.26920123415120002).

Abstract

Abstract:

A new coordination polymer {[Zn₂(dpb)₂(bdc)₂]·1.3H₂O}_n(1) was prepared under solvothermal condition using terephthalate(1,4-H₂bdc) as well as 1,3-dipyridyl benzene(1,3-dpb) as initiators. The complex was characterized by means of infrared spectroscopy(IR), thermogravimetric analysis(TGA), powder X^-ray diffraction(XRD) and X^-ray single-crystal diffraction. The results indicate that complex 1 crystallizes in the monoclinic system with space group of P2₁/c. The neighboring Zn(II) ions are linked by ligand dpb to form infinitely meso-helical or zigzag chains, which are further connected to form a two-fold interpenetrated 3D framework, in which there exists strong hydrogen bonds(O-H…O) between the interpenetrated frameworks. In addition, the solid-state fluorescence behavior of complex 1 was also discussed.

Key words: Coordination polymer, V-Shaped ligand, Solid-state fluorescence, Zinc

XU Jingyao, ZHANG Lei, SHAO Xueman, PAN Chengling, XU Jiqing. Structure and Fluorescence Property of a Two-fold Interpenetrated Three-dimensional Zn(II) Complex Constructed by Terephthalate and 1,3-Dipyridyl Benzene[J]. Chemical Research in Chinese Universities, 2015, 31(3): 328-331.

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Structure and Fluorescence Property of a Two-fold Interpenetrated Three-dimensional Zn(II) Complex Constructed by Terephthalate and 1,3-Dipyridyl Benzene

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