Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand

doi:10.1007/s40242-015-5015-4

Abstract

Abstract:

Two novel 2D coordination polymers, [Co(BPDC)DMSO]·DMSO(1)(BPDC=2,2'-bipyridyl-4,4'-dicar- boxylic acid) and [Zn(BPDC)DMF]·DMF(2), were synthesized from 2,2'-bipyridyl-4,4'-dicarboxylic acid ligand (H₂BPDC) under solvothermal conditions. Single crystal X-ray diffraction analyses reveal that compound 1 crystallizes in orthorhombic system and Pca2₁ space group with a=1.29628(13) nm, b=1.13721(13) nm, c=1.66457(19) nm, α=90°, β=90°, γ=90°, V=2.4538(5) nm³. Compound 2 crystallizes in monoclinic system and P2₁/c space group with a=0.9429(6) nm, b=1.4757(10) nm, c=1.5980(9) nm, α=90°, β=114°, γ=90°, V=2.030(2) nm³. Compounds 1 and 2 exhibit two different 3-connected hcb and fes topologies, respectively. The structures of the two compounds both contain interesting characters of double-helical chains(left- and right-handed helical chains). Additionally, the magnetic and luminescent properties of the two compounds were studied.

Key words: Coordination polymer, Helical chain, Magnetic property, Luminescent property

WANG Jing, LUO Xiaolong, YUAN Yang, ZHANG Lirong. Assembly of Two Coordination Polymers Based on 2,2'-Bipyridyl-4,4'-dicarboxylic Acid Ligand[J]. Chemical Research in Chinese Universities, 2015, 31(4): 503-507.

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