Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand

doi:10.1007/s40242-016-5365-6

Abstract

Abstract:

Two coordination polymers {[Co₃L₃(Me₂NH)₂]·(Me₂NH)}_n(1) and [CuL(bpy)]_n(2)(L=2,2'-biphenyl dicarboxylate ion, bpy=4,4'-bipyridine) were obtained and characterized. Compound 1 was synthesised via solvothermal method, with the L ligands adopting syn-syn-μ₂-η¹:η¹- and μ₂-η²-coordination modes and Co(II) centers being linked to form a 1D coordination chain with trinuclear Co₃ cluster as sub-units. Compound 2 was synthesized at room temperature, with the L ligand chelating the Cu(II) centers to form a 1D chain, which was further linked by the auxiliary 4,4'-bpy ligand to form a 3D coordination network. The results of variable temperature susceptibility studies reveal that there were ferromagnetic and antiferromagnetic interactions between the paramagnetic metal centers in compounds 1 and 2, respectively.

Key words: Coordination polymer, Crystal structure, Magnetic property

ZHANG Qingfen, ZHOU Zhongyuan, WANG Xuan, LU Jing. Syntheses, Structures and Magnetic Properties of Two Coordination Polymers Based on 2, 2-Biphenyldicarboxylate Ligand[J]. Chemical Research in Chinese Universities, 2016, 32(2): 165-171.

References

[1] Cheng X. N., Zhang W. X., Chen X. M., J. Am. Chem. Soc., 2007, 129, 15738
[2] Wang X. Y., Wang Z. M., Gao S., Chem. Commun., 2008, 281
[3] Ma L. F., Wang L. Y., Wang Y. Y., Batten S. R., Wang J. G., Inorg. Chem., 2009, 48, 915
[4] Mondal K. C., Kostakis G. E., Lan Y. H., Anson C. E., Powell A. K., Inorg. Chem., 2009, 48, 9205
[5] Pachfule P., Das P., Poddar P., Banerjee R., Inorg. Chem., 2011, 50, 3855
[6] Halder G. J., Kepert C. J., Moubaraki B., Murray K. S., Cashion J. D., Science, 2002, 298, 1762
[7] Zheng Y. Z., Xue W., Tong M. L., Chen X. M., Grandjean F., Long G. J., Inorg. Chem., 2008, 47, 4077
[8] Lama P., Aijaz A., Sańudo E. C., Bharadwaj P. K., Cryst. Growth Des., 2010, 10, 283
[9] Oullette W., Prosvirin A. V., Whitenack K., Dunbar K. R., Zubieta J., Angew. Chem. Int. Ed., 2009, 48, 2140
[10] Mereacre V. M., Ako A. M., Clerac R., Wernsdorfer W., Filoti G., Bartolome J., Anson C. E., Powell A. K., J. Am. Chem. Soc., 2007, 129, 9248
[11] Mishra A., Tasiopoulos A. J., Wernsdorfer W., Moushi E. E., Moulton B., Zaworotko M. J., Abboud K. A., Christou G., Inorg. Chem., 2008, 47, 4832
[12] Zeng M. H., Hu S., Chen Q., Xie G., Shuai Q., Gao S. L., Tang L. Y., Inorg. Chem., 2009, 48, 7070
[13] Li Y. X., Xue M., Huang L., Chen S. R., Qiu S. L., Chem. Res. Chinese Universities, 2013, 29(4), 611
[14] Hennigar T. L., MacQuarrie D. C., Losier P., Roger R. D., Zaworkto M. J., Chem. Commun., 1997, 972
[15] Jung O. S., Park S. H., Kim K. M., Jang H. G., Inorg. Chem., 1998, 37, 5781
[16] Matsumoto N., Motoda Y., Matsuo T., Nakashima T., Re N., Dahan F., Tuchagues J. P., Inorg. Chem., 1999, 38, 1165
[17] Pan L., Huang X. Y., Li J., Wu Y. G., Zheng N. W., Angew. Chem. Int. Ed., 2000, 39, 527
[18] Sun D. F., Cao R., Sun Y. Q., Bi W. H., Yuan D. Q., Shi Q., Li X., Chem. Commun., 2003, 1528
[19] Dalgarno S. J., Hardie M. J., Raston C. L., Cryst. Growth Des., 2004, 4, 227
[20] Zhang G. Yang G. Chen Q. Ma J. S., Cryst. Growth Des., 2005, 5, 661
[21] Feng P., Bu X., Stucky G. D., Nature, 1997, 388, 735
[22] Wang X. F., Zhang Y. B., Xue W., Qia X. L., Chen X. M., Cryst. Eng. Comm., 2010, 12, 3834
[23] Rao C. N. R., Natarajan S., Vaidhyanathan R., Angew. Chem. Int. Ed., 2004, 43, 1466
[24] Zaworotko M. J., Angew. Chem. Int. Ed., 2000, 39, 3052
[25] Delgado-Friedrichs O., O'Keeffe M., Yaghi O. M., Acta Crystallogr., 2003, A59, 22
[26] Robin A. Y., Fromm K. M., Coord. Chem. Rev., 2006, 250, 2127
[27] Tian H., Jia Q. X., Gao E. Q., Wang Q. L., Chem. Commun., 2010, 46, 5349
[28] Zhuang W. J., Sun H. L., Xu H. B., Wang Z. M., Gao S., Jin L. P., Chem. Commun., 2010, 46, 4339
[29] Sheldrich G. M., SHELXL 97, Program for Crystal Structure Refinement, University of Göttiingen, Göttiingen, 1997
[30] Ma Q., Zhu M. L., Lu L. P., Feng S. S., Wang T. W., Dalton Trans., 2010, 5877
[31] Feller R. K., Cheetham A. K., Dalton Trans., 2008, 2034
[32] Huang F. P., Tian J. L., Gu W., Liu X., Yan S. P., Liao D. Z., Cheng P., Cryst. Growth Des., 2010, 10, 1145
[33] Gu Z. G., Yang Q. F., Liu W., Song Y., Li Y. Z., Zuo J. L., You X. Z. Inorg. Chem., 2006, 45, 8895
[34] Niu C. Y., Zheng X. F., Wan X. S., Kou C. H., Cryst. Growth Des., 2011, 11, 2874
[35] Liu J. Q., Liu B., Wang Y. Y., Liu P., Yang G. P., Liu R. T., Shi Q. Z., Batten S. R., Inorg. Chem., 2010, 49, 10422
[36] Xiao D. R., Zhang G. J., Liu J. L., Fan L. L., Yuan R. M., Tong, L., Dalton Trans., 2011, 40, 5680
[37] Li H. J., Yao H. C., Zhang E. P., Jia Y. Y., Hou H. W., Fan Y. T., Dalton Trans., 2011, 40, 9388
[38] Shit S., Chakraborty J., Das A., Yap G. P. A., Fallah M. S. EI., Mitra S., Struct. Chem., 2007, 18, 317
[39] Du M., Guo Y. M., Bu X. H., Ribas J., Eur. J. Inorg. Chem., 2004, 3228
[40] Sakiyama H., Suzuki T., Ono K., Ito R., Watanabe Y., Yamasaki M., Mikuriya M., Inorg. Chim. Acta, 2005, 35, 1897
[41] Goodenough J. B., J. Phys. Chem. Solids, 1958, 6, 287
[42] Kanamori J., J. Phys. Chem. Solids, 1959, 10, 87
[43] Liu S. J., Xue L., Hu T. L., Bu X. H., Dalton Trans., 2012, 41, 6813