Template-directed Synthesis of Three Metal Oxalates via 4-Connected Building Units

doi:10.1007/s40242-014-4178-8

Chemical Research in Chinese Universities ›› 2014, Vol. 30 ›› Issue (6): 889-893.doi: 10.1007/s40242-014-4178-8

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Template-directed Synthesis of Three Metal Oxalates via 4-Connected Building Units

TIAN Ruijing¹, WANG Fuxiang¹, DU Chunyu¹, FENG Lijuan¹, LIU Ying¹, ZHANG Cailing¹, PAN Qinhe^1,2

1. Key Study Center of the National Ministry of Education for Tropical Resources Utilization, Department of Materials and Chemical Engineering, Hainan University, Haikou 570228, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2014-05-12 Revised:2014-06-20 Online:2014-12-01 Published:2014-06-30
Contact: PAN Qinhe E-mail:panqinhe@163.com
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21101047, 11204057), the Program for New Century Excellent Talents in Universities of China(No.NCET-11-0929), the Natural Science Foundation of Hainan Province, China(No. 112003), the Scientific Research Foundation in University of Hainan Province, China(No.Hjkj2012-06) and the Young Scientist Foundation of Hainan University, China(Nos.qnjj1237, qnjj1251).

Abstract

Abstract:

Three novel compounds, [Co(en)₃]₂[Zr₂(C₂O₄)₇]·2H₂O(HNU-2, en=ethylenediamine), [Co(NH₃)₆]·[Ce(C₂O₄)₃(H₂O)]·H₂O(HNU-3) and [Co(dien)₂][Gd(C₂O₄)₃]·0.75H₂O(HNU-4, dien=dethylenetriamine) were hydrothermal synthesized based on the templates of [Co(en)₃]Cl₃, [Co(NH₃)₆]Cl₃ and [Co(dien)₂]Cl₃, respectively. The Zr⁴⁺, Ce³⁺ and Gd³⁺ cations are all coordinated by four oxalates to form [M(C₂O₄)₄(H₂O)_n]^m^-(M=Zr, Ce or Gd; n=0 or 1; m=4 or 5), which are similar to [In(C₂O₄)₄]^5- in NKB-1, and can be regarded as 4-connected building units. The [M(C₂O₄)₄(H₂O)_n]^m^- units are connected via sharing the bis-bidentate bridging oxalate ligands to form binuclears in HNU-2 and 1D “zigzag” chains in HNU-3 and HNU-4. It is suggested that these compounds could be used as molecular building units to design 3D open frameworks with zeolite topologies.

Key words: Coordination polymer, Template-directed synthesis, Metal oxalate

TIAN Ruijing, WANG Fuxiang, DU Chunyu, FENG Lijuan, LIU Ying, ZHANG Cailing, PAN Qinhe. Template-directed Synthesis of Three Metal Oxalates via 4-Connected Building Units[J]. Chemical Research in Chinese Universities, 2014, 30(6): 889-893.

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Template-directed Synthesis of Three Metal Oxalates via 4-Connected Building Units

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