A Synergistic Strategy for Nanoparticle/Nanofiber Composites Towards p-Nitrophenol Catalytic Hydrogenation

doi:10.1007/s40242-015-5155-6

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (6): 1012-1017.doi: 10.1007/s40242-015-5155-6

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A Synergistic Strategy for Nanoparticle/Nanofiber Composites Towards p-Nitrophenol Catalytic Hydrogenation

WANG Wei¹, WANG Ke¹, HE Jiaojie¹, ZHANG Xintong¹, WANG Ce², ZHAO Zhiwei³, CUI Fuyi¹

1. State Key Laboratory of Urban Water Resource and Environment(SKLUWRE), School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, P. R. China;
2. Alan G. Macdiarmid Institute, Jilin University, Changchun 130012, P. R. China;
3. Department of National Defense Construction Planning and Environmental Engineering, Logistical Engineering University, Chongqing 401311, P. R. China

Received:2015-04-15 Revised:2015-05-19 Online:2015-11-01 Published:2015-08-14
Contact: WANG Ke, CUI Fuyi E-mail:hitwk@sina.com;cuifuyi@hit.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21304024), the Project of the State Key Laboratory of Urban Water Resource and Environment, China(No.2013TS06), the Fundamental Research Funds for the Central Universities of China (No.HIT.BRETIII.201417) and the Postdoctoral Science Foundation of China(No.2014T70324).

Abstract

Abstract:

Nanoparticle(NP)/nanofiber(NF) composites based on Ag/hydrostable-polyvinyl alcohol were fabricated by a green synergistic strategy via electrospinning. The electrospun NFs served as an in situ reducing agent for the metal salt precursors and a protecting agent for the resulting NPs. Additionallly, during the fomation of the NPs, the water-soluble NFs were in situ oxidized and catalyzed by the metal ions to achieve chemical crosslinking. This two-in-one process achieves polymer curing and metal nanoparticles reducing/protecting synergistically. It eliminates the usage of organic electrospinning solvents, conventional chemical reducing agents and stabilizers, as well as harmful chemical crosslinking agents during the whole process. By the absolutely green synergistic electrospinning, nanoparticle/nanofiber composites with super-hydrophilicity, good hydrostability, as well as uniform and thin particle sizes were obtained. They exhibited enhanced activities when used for catalytic hydrogenation of p-nitrophenol in water.

Key words: Electrospinning, Supported nanoparticle, Nanofiber, Ag

WANG Wei, WANG Ke, HE Jiaojie, ZHANG Xintong, WANG Ce, ZHAO Zhiwei, CUI Fuyi. A Synergistic Strategy for Nanoparticle/Nanofiber Composites Towards p-Nitrophenol Catalytic Hydrogenation[J]. Chemical Research in Chinese Universities, 2015, 31(6): 1012-1017.

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A Synergistic Strategy for Nanoparticle/Nanofiber Composites Towards p-Nitrophenol Catalytic Hydrogenation

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