N-Doped Carbon Nanofibers Encapsulating CoO@Co9S8 Nanoparticles: Preparation from S-Rich Co32 Coordination Cluster Precursors by Electrospinning and Application for Superior Li-ion Storage

doi:10.1007/s40242-021-1157-8

Abstract

Abstract: Thiacalixarene-supported Co₃₂nanoclusters encapsulated in polyacrylonitrile nanofibers(Co₃₂@PAN-NFs) by electrospinning have been utilized as precursors to fabricate N-doped CoO@Co₉S₈ carbon nanofibers(CoO@Co₉S₈@CNFs) for superior Li-ion storage. The S-rich Co₃₂ clusters capped by organic sheets afforded the well dispersed cobalt oxide/sulfide nanoparticles embedded in carbon nanofiber composites by direct calcination. The N-doped CoO@Co₉S₈@CNFs nanocomposites have been utilized as anode materials for lithium ion battery with the reversible capabilities being of 1051.8, 967.6, 894.7, 782.7, 669.5 and 525.4 mA·h/g at 0.1, 0.2, 0.5, 1, 2 and 3 A/g, respectively. The CoO@Co₉S₈@CNFs also showed a relatively high stable capacity of 551.7 mA·h/g at the current density of 1 A/g after 200 cycles of rate experiments. The as-obtained N-doped CoO@Co₉S₈@CNFs nanocomposites exhibited superior reversible capacity, rate performance, Coulomb efficiency(74.5% vs. 63.9%) and cyclic stability comparing with the CoO@Co₉S₈@C derived from simple annealing of Co₃₂templates.

Key words: Metal cluster precursor, Carbon nanofiber, Electrospinning, Li-ion storage

YANG Siran, AI Feixue, LI Ziping, ZHAO Guiyan, BI Yanfeng. N-Doped Carbon Nanofibers Encapsulating CoO@Co₉S₈ Nanoparticles: Preparation from S-Rich Co₃₂ Coordination Cluster Precursors by Electrospinning and Application for Superior Li-ion Storage[J]. Chemical Research in Chinese Universities, 2022, 38(2): 603-608.

References

[1] Rui X. H., Tan H. T., Yan Q. Y., Nanoscale, 2014, 6, 9889.
[2] Zhao J. B., Zhang Y. Y., Wang Y. H., Li H., Peng Y. Y., J. Energy Chem., 2018, 27, 1536.
[3] Xu X. D., Liu W., Kim Y., Cho J., Nano Today, 2014, 9, 604.
[4] Huang G. C., Chen T., Wang Z., Chang K., Chen W. X., J. Power Sources, 2013, 235, 122.
[5] Jin R. C., Zhou J. H., Guan Y. S., Liu H., Chen G., J. Mater. Chem. A, 2014, 2, 13241.
[6] Mahmood N., Zhang C. Z., Jiang J., Liu F., Hou Y. L., Chem-Eur J., 2013, 19, 5183.
[7] Zhou Y. L., Yan D., Xu H. Y., Feng J. K., Jiang X. L., Yue J., Yang J., Qian Y. T., Nano. Energy, 2015, 12, 528.
[8] Apostolova R. D., Shembel E. M., Talyosef I., Grinblat J., Markovsky B., Aurbach D., Russ. J. Electrochem+, 2009, 45, 311.
[9] Zeng P. Y., Li J. W., Ye M., Zhuo K. F., Fang Z., Chem-Eur J., 2017, 23, 9517.
[10] Tang X. K., Huang J., Feng Q. M., Liu K., Luo X. P., Li Z. S., Nanotechnology, 2017, 28, 375402.
[11] Wu R. B., Wang D. P., Rui X. H., Liu B., Zhou K., Law A. W. K., Yan Q. Y., Wei J., Chen Z., Adv. Mater., 2015, 27, 3038.
[12] Huang J., Tang X. K., Liu K., Li Z. S., Mater. Lett., 2018, 210, 88.
[13] Shi W. H., Zhu J. X., Rui X. H., Cao X. H., Chen C., Zhang H., Hng H. H., Yan Q. Y., ACS Appl. Mater. Inter., 2012, 4, 2999.
[14] Wang Y. H., Wu B. H., He X. Y., Zhang Y. Y., Li H., Peng Y. Y., Wang J., Zhao J. B., Electrochim. Acta, 2017, 230, 299.
[15] Zheng S. S., Li X. R., Yan B. Y., Hu Q., Xu Y. X., Xiao X., Xue H. G., Pang H., Adv. Energy Mater., 2017, 7, 1602733.
[16] Cao X. H., Tan C. L., Sindoro M., Zhang H., Chem. Soc. Rev., 2017, 46, 2660.
[17] Fang G. Z., Wu Z. X., Zhou J., Zhu C. Y., Cao X. X., Lin T. Q., Chen Y. M., Wang C., Pan A. Q., Liang S. Q., Adv. Energy. Mater., 2018, 8, 1703155.
[18] Yang Q. J., Liu Y., Xiao L. S., Yan M., Bai H. Y., Zhu F. F., Lei Y., Shi W. D., Chem. Eng. J., 2018, 354, 716.
[19] Yilmaz G., Yam K. M., Zhang C., Fan H. J., Ho G. W., Adv. Mater., 2017, 29, 1606814.
[20] Bi Y. F., Du S. C., Liao W. P., Coord. Chem. Rev., 2014, 276, 61.
[21] Hang X. X., Bi Y. F.,Dalton Trans., 2021,50, 3749.
[22] Shi C., Chen M. W., Han X., Bi Y. F., Huang L. L., Zhou K., Zheng Z. P., Inorg. Chem. Front., 2018,5, 1329.
[23] Han X., Ai F. X., Wang X., Chen B. K., Wang L. J., Bi Y. F., Polyhedron, 2019, 171, 279.
[24] Li W. H., Li M. S., Adair K. R., Sun X. L., Yu Y., J. Mater. Chem. A, 2017, 5, 13882.
[25] Li W. H., Zeng L. C., Wu Y., Yu Y., Sci. China Mater., 2016, 59, 287.
[26] Chen Y. M., Li X. Y., Park K., Zhou L. M., Huang H. T., Mai Y. M., Goodenough J. B.,Angew. Chem. Int. Ed., 2016, 55, 15831.
[27] Huang J. N., Cao Y. H., Huang Z. Y., Imbraguglio S. A., Wang Z., Peng X. F., Guo Z. H., Macromol. Mater. Eng., 2016, 301, 1327.
[28] Liu D., Zhang X. P., Sun Z. C., You T. Y., Nanoscale, 2013, 5, 9528.
[29] Wei K., Kim K. O., Song K. H., Kang C. Y., Lee J. S., Gopiraman M., Kim I. S., J. Mater. Sci. Technol., 2017, 33, 424.
[30] Bi Y. F., Wang X. T., Liao W. P., Wang X. F., Wang X. W., Zhang H. J., Gao S., J. Am. Chem. Soc., 2009, 131, 11650.
[31] Liu S. M., Wang J. X., Wang J. W., Zhang F. F., Wang L. M., Appl. Surf. Sci., 2016, 390, 86.
[32] Ren H. B., Gu C. P., Zhao J. J., Joo S. W., Huang J. R., Appl. Surf. Sci., 2019, 473, 918.
[33] Yang J., Yu C., Fan X. M., Liang S. X., Li S. F., Huang H. W., Ling Z., Hao C., Qiu J. S., Energy. Environ. Sci., 2016, 9, 1299.
[34] Qin W., Han L., Bi H., Jian J. H., Wu X. H., Guo P., Nanoscale, 2015, 7, 20180.
[35] Zheng F. C., Yang Y., Chen Q. W., Nat. Commun., 2014, 5, 5261.
[36] Liu J., Wu C., Xiao D. D., Kopold P., Gu L., van Aken P. A., Maier J., Yu Y., Small, 2016, 12, 2354.
[37] Wu Y. L., Zhu C., Shu L., Duan J. F., Wei D. H., Xu J. X., Zhu Z. Y., Li L. J., Peng Z. Y., Chen Z. Y., Appl. Surf. Sci., 2019, 489, 528.
[38] Wang Y. M., Wu J. J., Tang Y. F., Lü X. J., Yang C. Y., Qin M. S., Huang F. Q., Li X., Zhang X., ACS. Appl. Mater. Inter., 2012, 4, 4246.
[39] Nam K. T., Kim D. M., Yoo P. J., Chiang C. Y., Meethong N., Hammond P. T., Chiang Y. M., Belcher A. M., Science, 2006, 312, 885.
[40] Zhang Y. H., Wang N. N., Sun C. H., Lu Z. X., Xue P., Tang B., Bai Z. C., Dou S. X., Chem. Eng. J., 2018, 332, 370.
[41] Yan Z. H., Jiang L. L., Chen D. C., Huo B. Y., Zhou H. H., Huang Z. Y., Mater. Lett., 2021,282, 128850.

N-Doped Carbon Nanofibers Encapsulating CoO@Co₉S₈ Nanoparticles: Preparation from S-Rich Co₃₂ Coordination Cluster Precursors by Electrospinning and Application for Superior Li-ion Storage

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