Construction of a Ytterbium Supramolecular Compound from 5,5'-(Buta-diyne-1,4-diyl)diisophthalic Acid

doi:10.1007/s40242-014-4193-9

Abstract

Abstract:

A novel 3D ytterbium supramolecular compound, [Yb(HBDDC)(H₂O)₄]·2H₂O(1), was synthesized via 5,5'-(buta-diyne-1,4-diyl)diisophthalic acid ligand(H₄BDDC) under solvothermal conditions. Single-crystal X-ray diffraction analysis reveals that compound 1crystallizes in triclinic system, Pī space group with a=0.71372(14) nm, b=1.0566(2) nm, c=1.7969(4) nm, α=101.01(3)°, β=98.15(3)°, γ=99.17(3)° and V=1.2922(4) nm³. Compound 1 exhibits a special infinite 1D chain, which stacks parallel each other in an ABAB sequence, leading to the formation of a 3D supramolecular structure owing to the strong π-π interactions between adjacent phenyl ring groups. Moreover, compound 1 manifests excellent luminescent property.

Key words: Supramolecular compound, Solvothermal condition, Ytterbium, Luminescent property

WANG Jing, MU Li, ZHANG Jian, ZHAO Tingting, FAN Zhiqiang, ZHANG Lirong. Construction of a Ytterbium Supramolecular Compound from 5,5'-(Buta-diyne-1,4-diyl)diisophthalic Acid[J]. Chemical Research in Chinese Universities, 2014, 30(6): 885-888.

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