Direct Electrochemistry Transfer and Electrocatalysis of Hemoglobin Immobilized in Porous Mn2O3

Chemical Research in Chinese Universities ›› 2011, Vol. 27 ›› Issue (2): 291-294.

• Articles • Previous Articles Next Articles

Direct Electrochemistry Transfer and Electrocatalysis of Hemoglobin Immobilized in Porous Mn2O3

SHI Lin-pu² and GAO Qiu-ming^1,2*

1. School of Chemistry and Environment, Beihang University, Beijing 100191, P. R. China;
2. Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China

Received:2010-09-16 Revised:2010-12-06 Online:2011-03-25 Published:2011-05-26
Contact: GAO Qiu-ming E-mail:qmgao@buaa.edu.cn
Supported by:
Supported by the National Basic Research Program of China(No.2011CB935700) and the National Natural Science Foundation of China(No.U0734002).

Abstract

Abstract: Novel porous Mn2O3 with good crystallinity was synthesized via hard-template method. Hb-Mn2O3 nanocomposite was prepared and used for biosensor construction. The Hb-Mn2O3-Nafion modified electrode shows fast direct electron transfer and displays good electrocatalytic response to the reduction of H2O2. The response time is less than 5 s, the sensitivity is as high as 493 μA·L·mmol–1·cm–2 in a linear range of 1—100 μmol/L, and the detection limit is 0.16 μmol/L. This modified electrode also shows good stability and reproducibility. This indicates that the porous Mn2O3 provides a good matrix for enzyme immobilization and biosensor construction.

Key words: Porous Mn2O3, Biosensor, Direct electrochemistry, Electrocatalysis, Hemoglobin

SHI Lin-pu and GAO Qiu-ming*. Direct Electrochemistry Transfer and Electrocatalysis of Hemoglobin Immobilized in Porous Mn2O3[J]. Chemical Research in Chinese Universities, 2011, 27(2): 291-294.

[1]	MA Chunrong, SONG Bingyi, MA Zhentao, WANG Xiaoqian, TIAN Lin, ZHANG Haoran, CHEN Cai, ZHENG Xusheng, YANG Li-ming, WU Yuen. A Supported Palladium on Gallium-based Liquid Metal Catalyst for Enhanced Oxygen Reduction Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1219-1225.
[2]	TANG Tianwei, LIU Yinghuan, JIANG Ying. Recent Progress on Highly Selective and Sensitive Electrochemical Aptamer-based Sensors [J]. Chemical Research in Chinese Universities, 2022, 38(4): 866-878.
[3]	CHANG Kaili, SUN Peng, DONG Xin, ZHU Chunnan, LIU Xiaojun, ZHENG Dongyun, LIU Chao. Aptamers as Recognition Elements for Electrochemical Detection of Exosomes [J]. Chemical Research in Chinese Universities, 2022, 38(4): 879-885.
[4]	SHEN Congcong, CHEN Yuehua, FENG Beidou, CHI Hongying, ZHANG Hua. Polypyrrole Hollow Nanotubes Loaded with Au and Fe₃O₄ Nanoparticles for Simultaneous Determination of Ascorbic Acid, Dopamine, and Uric Acid [J]. Chemical Research in Chinese Universities, 2022, 38(4): 941-948.
[5]	HAO Zhimin, LIU Dapeng, GE Huaiyun, ZUO Xintao, FENG Xilan, SHAO Mingzhe, YU Haohan, YUAN Guobao, and ZHANG Yu. Preparation of Quaternary FeCoMoCu Metal Oxides for Oxygen Evolution Reaction [J]. Chemical Research in Chinese Universities, 2022, 38(3): 823-828.
[6]	FU Xinliang, ZHU Aonan, CHEN Xiaojie, ZHANG Shifu, WANG Mei, YUAN Mingjian. Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction [J]. Chemical Research in Chinese Universities, 2021, 37(6): 1328-1333.
[7]	LIU Zhenyu, DONG Jinyi, PAN Jiahao, ZHOU Chao, FAN Chunhai, WANG Qiangbin. Catalytic DNA Origami-based Chiral Plasmonic Biosensor [J]. Chemical Research in Chinese Universities, 2021, 37(4): 914-918.
[8]	YUAN Fang, LI Yang, CHEN Zhenjuan, ZHANG Jianjian, NING Lulu, YANG Xiao-Feng, PU Kanyi. Excimer-based Activatable Fluorescent Sensor for Sensitive Detection of Alkaline Phosphatase [J]. Chemical Research in Chinese Universities, 2021, 37(4): 960-966.
[9]	WEN Jinguli, LI Yuwen, GAO Junkuo. Two-dimensional Metal-Organic Frameworks and Derivatives for Electrocatalysis [J]. Chemical Research in Chinese Universities, 2020, 36(4): 662-679.
[10]	SUN Rongbo, GUO Wenxin, HAN Xiao, HONG Xun. Two-dimensional Noble Metal Nanomaterials for Electrocatalysis [J]. Chemical Research in Chinese Universities, 2020, 36(4): 597-610.
[11]	FANG Wensheng, HUANG Lei, ZAMAN Shahid, WANG Zhitong, HAN Youjia, XIA Bao Yu. Recent Progress on Two-dimensional Electrocatalysis [J]. Chemical Research in Chinese Universities, 2020, 36(4): 611-621.
[12]	LEI Jia, ZENG Mengqi, FU Lei. Two-dimensional Metal-Organic Frameworks as Electrocatalysts for Oxygen Evolution Reaction [J]. Chemical Research in Chinese Universities, 2020, 36(4): 504-510.
[13]	DONG Wenfei, CHEN Xiaoyu, PENG Juan, LIU Wanyi, JIN Xiaoyong, NI Gang, LIU Zheng. Recent Progress on 2D Transition Metal Compounds-based Electrocatalysts for Efficient Nitrogen Reduction [J]. Chemical Research in Chinese Universities, 2020, 36(4): 648-661.
[14]	SHI Yi, DAI Wenrui, WANG Meng, XING Yongfang, XIA Xinghua, CHEN Wei. Bioinspired Construction of Ruthenium-decorated Nitrogen-doped Graphene Aerogel as an Efficient Electrocatalyst for Hydrogen Evolution Reaction [J]. Chemical Research in Chinese Universities, 2020, 36(4): 709-714.
[15]	YANG Chan, CHAI Jiaxin, WANG Zhe, XING Yonglei, PENG Juan, YAN Qingyu. Recent Progress on Bismuth-based Nanomaterials for Electrocatalytic Carbon Dioxide Reduction [J]. Chemical Research in Chinese Universities, 2020, 36(3): 410-419.

Direct Electrochemistry Transfer and Electrocatalysis of Hemoglobin Immobilized in Porous Mn2O3

PDF (PC)

Knowledge

Cited

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments