Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO2 Reduction

doi:10.1007/s40242-021-1344-7

Chemical Research in Chinese Universities ›› 2021, Vol. 37 ›› Issue (6): 1328-1333.doi: 10.1007/s40242-021-1344-7

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Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction

FU Xinliang¹, ZHU Aonan¹, CHEN Xiaojie¹, ZHANG Shifu², WANG Mei², YUAN Mingjian¹

1. Key Laboratory of Advanced Energy Materials Chemistry, Ministry of Education, Renewable Energy Conversion and Storage Center(RECAST), College of Chemistry, Nankai University, Tianjin 300071, P. R. China;
2. Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, P. R. China

Received:2021-08-29 Revised:2021-09-30 Online:2021-11-23 Published:2021-11-23
Contact: WANG Mei, YUAN Mingjian E-mail:meiwang@ouc.edu.cn;yuanmj@nankai.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.21771114, 91956130) and the Distinguished Young Scholars of Tianjin, China(No.19JCJQJC62000).

Abstract

Abstract: Electrocatalysis has become an attractive strategy for the artificial reduction of CO₂ to high-value chemicals. However, the design and development of highly selective and stable non-noble metal electrocatalysts that convert CO₂ to CO are still a challenge. As a new type of two-dimensional carbon material, graphdiyne(GDY), is rarely used to explore the application in carbon dioxide reduction reaction(CO₂RR). Therefore, we tried to use GDY as a substrate to stabilize the copper-nickel alloy nanoparticles(NPs) to synthesize Cu/Ni@GDY. Cu/Ni@GDY requires an overpotential (-0.61 V) to 10 mA/cm² for the formation of CO, and it shows better activity than Au and Ag, achieving a higher Faraday efficiency of about 95.2% and high stability of about 26 h at an overpotential (-0.70 V). The electronic interaction between GDY substrate and Cu/Ni alloy NPs and the large specific surface area of GDY is responsible for the high performance.

Key words: Graphdiyne(GDY), Carbon dioxide reduction reaction (CO₂RR), CO, Electrocatalysis, Cu/Ni alloy nanoparticle

FU Xinliang, ZHU Aonan, CHEN Xiaojie, ZHANG Shifu, WANG Mei, YUAN Mingjian. Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction[J]. Chemical Research in Chinese Universities, 2021, 37(6): 1328-1333.

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Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction

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