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Chemical Research in Chinese Universities ›› 2002, Vol. 18 ›› Issue (4): 385-388.

• Articles • Previous Articles     Next Articles

Hydrothermal Synthesis and Characterization of a Novel Supramolecular Network Compound [Co(IN)2(H2O)4](IN=Isonicotinate)

JIA Hong-bin1,3, YU Jie-hui1, DING Hong1, XU Ji-qing1, YE Ling2, JING Wei-jie1, WANG Tie-gang1, XU Jia-ning1, QU Xue-jian1, LI Zeng-chun1,3   

  1. 1. College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China;
    2. Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, P. R. China;
    3. Department of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028000, P. R. China
  • Received:2002-01-18 Online:2002-12-24 Published:2011-08-04
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.29733090), the Research Funds for the Doctoral Program of Higher Education, the State Key Laboratory of Coordination Chemistry, Nanjing University and the Funds of Inner Mongolia Education Bureau, China(No.209925).

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Abstract: A novel supramolecular compound, [Co(IN)2(H2O)4](1), was synthesized by means of the hydrothermal method and its structure was characterized with elemental analysis, FT-IR spectrum, TGA and X-ray diffraction. Though the unit cell structure of the title compound is only monomeric, all these units as building blocks are assembled into a novel three-dimensional supramolecular network via the widely hydrogen-bonding and π-π stacking interactions.

Key words: Hydrothermal synthesis, Cobalt(Ⅱ) complex, X-Ray diffraction, Isonicotinate, Supramolecule