Hydrothermal Syntheses and Characterization of Two 1D Chain Complexes and Tetra-capped Keggin Clusters

doi:10.1007/s40242-015-4325-x

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (1): 4-8.doi: 10.1007/s40242-015-4325-x

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Hydrothermal Syntheses and Characterization of Two 1D Chain Complexes and Tetra-capped Keggin Clusters

LIU Yabing^1,2, DUAN Weijie², CUI Xiaobing², XU Jiqing²

1. Department of Materials Science and Engineering, Jilin Jianzhu University, Changchun 130118, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2014-08-28 Revised:2014-09-29 Online:2015-02-01 Published:2014-10-20
Contact: LIU Yabing, E-mail:liuyab@163.com E-mail:liuyab@163.com
Supported by:
Supported by the National Natural Science Foundation of China(No.20771030) and the Natural Science Foundation of Jilin Province, China(No.201215173).

Abstract

Abstract:

Two new compounds, [Ni(en)₂]{[Ni(en)₂]₂[Mo^VI₆Mo^V₂V^IV₈O₄₀(SiO₄)]}[(NH₂)₂(C₂H₄)₂NH]·2H₂O(1) and [Ni(en)₂]{[Ni(en)₂]₂[Mo^VI₅Mo^V₃V^IV₈O₄₀(VO₄)]}(en)·H₂O(2)(en=ethylenediamine), have been hydrothermally synthesized and characterized by elemental analysis, infrared(IR), X-ray photoelectron spectroscopy(XPS), electron spin-resonance(ESR) and thermogravimetric(TG) analysis and single-crystal X-ray diffraction(XRD) analysis. Both the compounds exhibit a 1D chain composed of bi-supporting tetra-capped Keggin clusters and nickle coordination fragments. The 1D chains are further assembled into a 3D supramolecular network with different packing modes via hydrogen bonds. The magnetic susceptibility of compound 1 demonstrates the presence of antiferromagnetic interactions.

Key words: Hydrothermal synthesis, Polyoxometalate, Tetra-capped Keggin cluster, Magnetic susceptibility

LIU Yabing, DUAN Weijie, CUI Xiaobing, XU Jiqing. Hydrothermal Syntheses and Characterization of Two 1D Chain Complexes and Tetra-capped Keggin Clusters[J]. Chemical Research in Chinese Universities, 2015, 31(1): 4-8.

References

[1] Pope M. T., Heteropoly and Isopolyoxometalates, Springer-Verlag, Berlin, 1983, 147
[2] Davis M. E., Nature, 2002, 417, 813
[3] Mizuno N., Misono M., Chem. Rev., 1998, 98, 199
[4] Wu Q., Chen W. L., Liu D., Liang C., Li Y. G., Lin S. W., Wang E. B., Dalton Trans., 2011, 40, 56
[5] Zheng S. T., Zhang J., Li X. X., Fang W. H., Yang G. Y., J. Am. Chem. Soc., 2010, 132, 15102
[6] Wang X., Peng J., Liu M. G., Wang D. D., Meng C. L., Li Y., Shi Z. Y., CrystEngComm, 2012, 14, 3220
[7] Cui X. B., Xu J. Q., Meng H., Zheng S. T., Yang G. Y., Inorg. Chem., 2004, 43, 8005
[8] Guo H., Yu K., Su Z. H., Wang C. M., Wang C. X., Zhou B. B., Inorg. Chem. Commun., 2013, 27, 43
[9] Wu H., Yang J., Liu Y. Y., Ma J. F., Cryst. Growth Des., 2012, 12, 2272
[10] Ren Y. P., Kong X. J., Long L. S., Huang R. B., Zheng L. S., Cryst. Growth Des., 2006, 6, 572
[11] Wang X. L., Li J., Tian A. X., Zhao D., Liu G. C., Lin H. Y., Cryst. Growth Des., 2011, 11, 3456
[12] Zhang Y., Chen L., Ju W. W., Xu Y., Chem. Res. Chinese Unversities, 2014, 30(2), 194
[13] Liu C. M., Luo J. L., Zhang D. Q., Wang N. L., Chen Z. J., Zhu D. B., Eur. J. Inorg. Chem., 2004, 4774
[14] Liu Y. B., Cui X. B., Xu J. Q., Lu Y. K., Liu J., Zhang Q. B., Wang T. G., J. Mol. Struct., 2006, 825, 45
[15] Sha J. Q., Peng J., Liu H. S., Chen J., Tian A. X., Zhang P. P., Inorg. Chem., 2007, 46, 11183
[16] Wang X. N., Liu S. X., Li S. J., Xie R. H., Zhang X., Liu Y. W., Chem. J. Chinese Universities, 2013, 34(5), 1047
[17] Cui X. B., Zheng S. T., Sun Y. Q., Yang G. Y., Chem. Res. Chinese Universities, 2004, 20(1), 10
[18] Wang L., Wang Y. Y., Li Y., Liang Z. Q., Chem. J. Chinese Universities, 2012, 33(8), 1646
[19] Liu C. M., Zhang D. Q., Zhu D. B., Cryst. Growth Des., 2005, 5, 1639
[20] Liu C. M., Zhang D. Q., Xiong M., Zhu D. B., Chem. Commun., 2002, 1416
[21] Shi Z. Y., Gu X. J., Peng J., Xu Y., Wang E. B., Eur. J. Inorg. Chem., 2006, 385
[22] Niu J. Y., Chen G., Zhao J. W., Yu C. F., Ma P. T., Wang J. P., Cryst. Growth Des., 2010, 10, 4689
[23] Liu J., Xu J. N., Liu Y. B., Lu Y. K., Song J. F., Zhang X., Cui X. B., Xu J. Q., Wang T. G., J. Solid State Chem., 2007, 180, 3456
[24] Yuan M., Li Y. G., Wang E. B., Tian C. C., Wang L., Hu C. W., Hu N. H., Jia H. Q., Inorg. Chem., 2003, 42, 3670
[25] Feng S. H., Xu R. R., Acc. Chem. Res., 2001, 34, 239
[26] Sheldrick C. M., SHELX-97, Program for Crystal Structure Solution, University of Göttingen, Göttingen, 1997
[27] Xu Y., Zhu H. G., Cai H., You X. Z., Chem. Commun., 1999, 787
[28] Brown I. D., Structure and Bonding in Crystals, Academic Press, New York, 1981, 2, 1
[29] Kahn O., Molecular Magnetism, Wiley-VCH, New York, 1993, 241

Hydrothermal Syntheses and Characterization of Two 1D Chain Complexes and Tetra-capped Keggin Clusters

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