Hydrothermal Synthesis and Magnetic Properties ofSmCr0.5M0.5O3(M=Fe and Mn) Micro-plates

doi:10.1007/s40242-017-7334-0

Abstract

Abstract: Nanostructured B-site Fe and Mn doped SmCrO₃ was prepared by mild hydrothermal growth. The as-prepared crystals are mainly micrometer-scale plates, ranging from rhombus(SmCr_0.5Fe_0.5O₃) to elongated he- xagonal(SmCr_0.5Mn_0.5O₃), and finally to well-edged rectangular(SmCr_0.17Mn_0.5Fe_0.33O₃) plates. Fe and Mn doped SmCrO₃ crystals are indexed into Pbnm space group. The cell parameters of SmCr_0.5Fe_0.5O₃ are slightly smaller than that of pristine SmCrO₃. Binding energy analysis of Cr, Mn and Fe in SmCr_0.17Mn_0.5Fe_0.33O₃ sample indicates that they all possess +3 oxidation states. Temperature dependent magnetization of the as-prepared samples presents obviously stronger ferromagnetic interactions than the undoped counterparts. This work represents a remarkable development for hydrothermal synthesis into fabricating perovskite oxide crystals with uniform distribution of doping ions.

Key words: Hydrothermal synthesis, Perovskite structure, B-Site ordering, Magnetic property

ZHANG Jiaqi, WANG Shan, YUAN Long, HOU Changmin. Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates[J]. Chemical Research in Chinese Universities, 2018, 34(1): 1-7.

References

[1] Peña M. A., Fierro J. L. G., Chem. Rev., 2001, 101, 1981
[2] Moritomo Y., Asamitsu A., Kuwahara H., Tokura Y., Nature, 1996, 380, 141
[3] Eerenstein W., Mathur N. D., Scott J. F., Nature, 2006, 442, 759
[4] Rao C. N. R., Sundaresan A., Saha R., J. Phys. Chem. Lett., 2012, 3, 2237
[5] Arakawa T., Kurachi H., Shiokawa J., J. Mater. Sci., 1985, 20, 1207
[6] Siemons M., Leifert A., Simon U., Adv. Funct. Mater., 2007, 17, 2189
[7] Huang K., Chu X., Feng W., Zhou C., Si W., Wu X., Yuan L., Feng S., Chem. Eng. J., 2014, 244, 27
[8] Huang K., Chu X., Yuan L., Feng W., Wu X., Wang X., Feng S., Chem. Commun., 2014, 50, 9200
[9] Tao S., Irvine J. T. S., Nat. Mater., 2003, 2, 320
[10] Goodenough J. B., Phys. Rev., 1955, 100, 564
[11] Mira J., Rivas J., Rivadulla F., Vázquez-Vázquez C., López-Quintela M. A., Phys. Rev. B, 1999, 60, 2998
[12] Feng S., Yuan H., Shi Z., Chen Y., Wang Y., Huang K., Hou C., Li J., Pang G., Hou Y., J. Mater. Sci., 2008, 43, 2131
[13] Ueda K., Tabata H., Kawai T., Science, 1998, 280, 1064
[14] Sahu J. R., Serrao C. R., Ray N., Waghmare U. V., Rao C. N. R., J. Mater. Chem., 2007, 17, 42
[15] Lee J. H., Jeong Y. K., Park J. H., Oak M. A., Jang H. M., Son J. Y., Scott J. F., Phys. Rev. Lett., 2011, 107, 117201
[16] Jung J. S., Iyama A., Nakamura H., Mizumaki M., Kawamura N., Wakabayashi Y., Kimura T., Phys. Rev. B, 2010, 82, 212403
[17] O'Flynn D., Tomy C. V., Lees M. R., Daoud-Aladine A., Balakrishnan G., Phys. Rev. B, 2011, 83, 174426
[18] Villafuerte-Castrejón M. E., García-Guaderrama M., Fuentes L., Prado-Gonjal J., González A. M., de la Rubia M. Á., García-Hernández M., Morán E., Inorg. Chem., 2011, 50, 8340
[19] Kanamori J., J. Phys. Chem. Solids, 1959, 10, 87
[20] Goodenough J. B., Phys. Rev., 1955, 100, 564
[21] Hu W., Chen Y., Yuan H., Zhang G., Li G., Pang G., Feng S., J. Solid State Chem., 2010, 183, 1582
[22] Rajeswaran B., Mandal P., Saha R., Suard E., Sundaresan A., Rao C. N. R., Chem. Mater., 2012, 24, 3591
[23] Serrao C. R., Kundu A. K., Krupanidhi S. B., Waghmare U. V., Rao C. N. R., Phys. Rev. B, 2005, 72, 220101
[24] Judin V. M., Sherman A. B., Myl'nikova I. E., Phys. Lett., 1966, 22, 554
[25] Feng S., Xu R., Acc. Chem. Res., 2001, 34, 239
[26] Modeshia D. R., Walton R. I., Chem. Soc. Rev., 2010, 39, 4303
[27] Sardar K., Lees M. R., Kashtiban R. J., Sloan J., Walton R. I., Chem. Mater., 2011, 23, 48
[28] Chen Y., Yuan H., Li G., Tian G., Feng S., J. Cryst. Growth, 2007, 305, 242
[29] Zhou Z., Guo L., Yang H., Liu Q., Ye F., J. Alloys Comp., 2014, 583, 21
[30] Yuan L., Huang K., Hou C., Feng W., Wang S., Zhou C., Feng S., New J. Chem., 2014, 38, 1168
[31] Wang S., Huang K., Hou C., Yuan L., Wu X., Lu D., Dalton Trans., 2015, 44, 17201
[32] Yuan L., Huang K., Wang S., Hou C., Wu X., Zou B., Feng S., Cryst. Growth Des., 2016, 16, 6522
[33] Bakshi V. R., Prasad B. V., Gade N. R., Chou F. C., Devarasetty S. B., AIP Conf. Proc., 2014, 1591, 1735
[34] Nashim A., Parida K. M., Chem. Eng. J., 2013, 215/216, 608
[35] Aono H., Sato M., Traversa E., Sakamoto M., Sadaoka Y., J. Am. Ceram. Soc., 2001, 84, 341
[36] Sivasubramanian V., Rama Rao M. V., Shripathi T., Subramanian V., Murthy V. R. K., Mater. Sci. Eng., 2000, B77, 128
[37] Gorodetsky G., Hornreich R. M., Shaft S., Sharon B., Shaulov A., Wanklyn B. M., Phys. Rev. B, 1977, 16, 515
[38] Cheng J. G., Zhou J. S., Goodenough J. B., Su Y. T., Sui Y., Ren Y., Phys. Rev. B, 2011, 84, 104415
[39] Marshall L. G., Cheng J. G., Zhou J. S., Goodenough J. B., Yan J. Q., Mandrus D. G., Phys. Rev. B, 2012, 86, 064417
[40] Fang Y., Yan S. M., Gong Y. Y., Zhu W. L., Cao Q. Q., Wang D. H., Du Y. W., Chin. Phys. B, 2014, 23, 127502
[41] Dash B. B., Ravi S., J. Magn. Magn. Mater., 2016, 405, 209

Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates

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