Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF4(2,2'-bipyridine)(H2O)2

doi:10.1007/s40242-015-4171-x

Chemical Research in Chinese Universities ›› 2015, Vol. 31 ›› Issue (1): 16-20.doi: 10.1007/s40242-015-4171-x

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Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂

Mouna SMIDA^1,2, Hager LITAIEM¹, Mohamed DAMMAK¹, Santiago GARCIA-GRANDA²

1. Laboratoire de Chimie Inorganique, Faculté des Sciences de Sfax, Université de Sfax, 3000Sfax, Tunisie;
2. Département de Chimie, Physique Analytique, Faculté de Chimie, Université d'Oviedo-CINN, 33006 Oviedo, Spain

Received:2014-05-05 Revised:2014-05-30 Online:2015-02-01 Published:2015-01-21
Contact: Mouna SMIDA, E-mail:mouna.smida@yahoo.fr E-mail:mouna.smida@yahoo.fr
Supported by:
Supported by the Project from the Ministry of Superior Education and the Research of Tunisia and Spanish MINECO (No. MAT2006-150AM).

Abstract

Abstract:

New crystal of FeF₄(2,2'-bipyridine)(H₂O)₂ was prepared by hydrothermal synthesis. Crystalline structure determination is performed from single crystal X-ray diffraction data. The unit cell is monoclinic space group P2₁/n, with cell parameters a=0.9046(5) nm, b=0.7502(5) nm, c=1.9539(5) nm, β=93.307(5)°, V=1.3238(12) nm³ and Z=4. The structure of FeF₄(2,2'-bipyridine)(H₂O)₂ is built up from FeF₄N₂ octahedra coordinated by two nitrogen atoms of the 2,2'-bipyridine molecules, and four fluorine atoms as well as uncoordinated H₂O molecules. Thermal analysis of the title compound showed that the decomposition introduced four steps. IR spectra confirmed the presence of 2,2'-bipyridine molecules. The optical absorption was measured at the corresponding l_max using UV-Vis diffuse reflectance spectrum.

Key words: Hydrothermal synthesis, Hybrid, Iron fluoride

Mouna SMIDA, Hager LITAIEM, Mohamed DAMMAK, Santiago GARCIA-GRANDA. Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂[J]. Chemical Research in Chinese Universities, 2015, 31(1): 16-20.

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Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂

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