Hydrothermal Synthesis of a New Zinc Phosphite (C5H7N2)2·[Zn3(HPO3)4] with Intersecting 8- and 12-Ring Channels

doi:10.1007/s40242-015-5021-6

Abstract

Abstract:

Using 4-aminopyridine as the structure-directing agent(SDA), a new open-framework zinc phosphite, (C₅H₇N₂)₂·[Zn₃(HPO₃)₄](ZnHPO-CJ70), was synthesized under hydrothermal condition. Single-crystal X-ray diffraction analysis reveals that ZnHPO-CJ70 is constructed by the strictly alternating ZnO₄ tetrahedra and HPO₃ pseudo-pyramids, with their vertexes linked to generate a three-dimensional(3D) open framework with intersecting 8- and 12-ring channels. Further characterizations of ZnHPO-CJ70 were performed by means of X-ray powder diffraction(XRD), elemental analysis(ICP, CHN), infrared spectroscopy(IR) and thermogravimetric(TG) analyses. The results of luminescent test shows that ZnHPO-CJ70 exhibits strong fluorescence emissions in the solid state at room temperature.

Key words: Hydrothermal synthesis, Zinc phosphite, Open framework, Photoluminescence

DONG Zhaojun, YAN Yan, ZHANG Wenqing, WANG Yu, LI Jiyang. Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels[J]. Chemical Research in Chinese Universities, 2015, 31(4): 498-502.

References

[1] Li Y., Yu J. H., Chem. Rev., 2014, 114(14), 7268
[2] Li Y., Yu J. H., Xu R. R., Baerlocher C., McCusker L. B., Angew. Chem. Int. Ed., 2008, 47, 4401
[3] Li Y., Yu J. H., Xu R. R., Angew. Chem. Int. Ed., 2013, 52, 1673
[4] Mallouk T. E., Gavin J. A., Acc. Chem. Res., 1998, 31(5), 209
[5] Seo J. S., Whang D., Lee H., Jeon Y. J., Kim K., Nature, 2000, 404, 982
[6] Cao G., Garcia M. E., Alcalá M., Burgess L. F., Mallouk T. E., J. Am. Chem. Soc., 1992, 114(19), 7574
[7] Joy A., Uppili S., Netherton M. R., Scheffer J. R., Ramamurthy V., J. Am. Chem. Soc., 2000, 122(4), 728
[8] Yu J. H., Xu R. R., Chem. Soc. Rev., 2006, 35, 593
[9] Yu J. H., Xu R. R., Acc. Chem. Res., 2010, 43(9), 1195
[10] Wang Z. P., Yu J. H., Xu R. R., Chem. Soc. Rev., 2012, 41, 1729
[11] Song X. W., Li Y., Gan L., Wang Z. P., Yu J. H., Xu R. R., Angew. Chem. Int. Ed., 2009, 48, 314
[12] Chiang R. K., Chuang N. T., J. Solid State Chem., 2005, 178(10), 3040
[13] Luo X. C., Luo D. B., Gong M. C., Chen Y. Q., Lin Z. E., Cryst. Eng. Comm., 2011, 13(11), 3646
[14] Zhao L., Li J. Y., Chen P., Li G. H., Yu J. H., Xu R. R., Chem. Mater., 2008, 20(1), 17
[15] Xing H. Z., Yang W. T., Su T., Li Y., Xu J., Nakano T., Yu J. H., Xu R. R., Angew. Chem. Int. Ed., 2010, 49(13), 2328
[16] Luo X. C., Luo D. B., Zeng H. M., Gong M. C., Chen Y. Q., Lin Z. E., Inorg. Chem., 2011, 50(18), 8697
[17] Lin H. Y., Chin C. Y., Huang H. L., Huang W. Y., Sie M. J., Huang L. H., Lee Y. H., Lin C. H., Lii K. H., Bu X. H., Wang S. L., Science, 2013, 339, 811
[18] Harrison W. T. A., J. Solid State Chem., 2001, 160(1), 4
[19] Harrison W. T. A., Phillips M. L. F., Nenoff T. M., Int. J. Inorg. Mater., 2001, 3(7), 1033
[20] Lin Z. E., Zhang J., Zheng S. T., Yang G. Y., J. Mater. Chem., 2004, 14, 1652
[21] Chen W. B., Li N., Xiang S. H., J. Solid State Chem., 2004, 177(9), 3229
[22] Wang X. L., Yan Y., Wu J. B., Zou Y. C., Zhang C. Q., Li J. Y., Chem. J. Chinese Universities, 2014, 35(6), 1142
[23] Fernández S., Mesa J. L., Lezama L., Arriortua M. I., Rojo T., Chem. Mater., 2002, 14(5), 2300
[24] Fernández S., Mesa J. L., Pizarro J. L., Lezama L., Arriortua M. I., Rojo T., Chem. Mater., 2003, 15(5), 1204
[25] Zhang D., Yue H. J., Shi Z., Guo M., Feng S. H., Micropor. Mesopor. Mater., 2005, 82(1/2), 209
[26] Fan J., Yee G. T., Wang G. B., Hanson B. E., Inorg. Chem., 2006, 45(2), 599
[27] Li G. J., Xing Y., Song S. Y., J. Solid State Chem., 2008, 181(4), 943
[28] Liu X. C., Xing Y., Liu X. Z., Cryst. Eng. Comm, 2010, 12, 383
[29] Liu X. C., Xing Y., Wang X. L., Xu H. B., Liu X. Z., Shao K. Z., Su Z. M., Chem. Commun., 2010, 46, 2614
[30] Mandal S., Pati S. K., Green M. A., Natarajan S., Chem. Mater., 2005, 17(3), 638
[31] Fan Y., Song T. Y., Li G. H., Shi Z., Yu G. H., Xu J. N., Feng S. H., Inorg. Chem. Commun., 2005, 8(8), 661
[32] Fernández S., Mesa J. L., Pizarro J. L., Lezama L., Arriortua M. I., Olazcuaga R., Rojo T., Chem. Mater., 2000, 12(8), 2092
[33] Fernández S., Pizarro J. L., Mesa J. L., Lezama L., Olazcuaga R., Rojo T., Inorg. Chem., 2001, 40(14), 3476
[34] Li N., Xiang S. H., J. Mater. Chem., 2002, 12, 1397
[35] Li N., Ma Y. F., Xiang S. H., Guan N. J., Chem. Mater., 2006, 18(4), 975
[36] Lu A. L., Song H. B., Li N., Xiang S. H., Guan N. J., Wang H. G., Chem. Mater., 2007, 19(17), 4142
[37] Xiang Y., Zhang L.W., Chen W. H., Chen J. Z., Zeng Q. X., Z. Anorg. Allg. Chem., 2007, 633(10), 1727
[38] Harrison W. T. A., Phillips M. L. F., Stanchfield J., Nenoff T. M., Inorg. Chem., 2001, 40(5), 895
[39] Liang J., Li J. Y., Yu J. H., Chen P., Fang Q. R., Sun F. X., Xu R. R., Angew. Chem. Int. Chem., 2006, 45(16), 2546
[40] Lai Y. L., Lii K. H., Wang S. L., J. Am. Chem. Soc., 2007, 129(17), 5350
[41] Gordon L. E., Harrison W. T. A., Inorg. Chem., 2004, 43(6), 1808
[42] Liu L., Zhang L. R., Wang X. F., Li G. H., Liu Y. L., Pang W. Q., Dalton Trans., 2008, 2009
[43] Sheldrick G. M., SAINT, Bruker AXS Inc., Madison, WI, 2000
[44] Sheldrick G. M., SHELXTL-97, Bruker AXS Inc., Madison, WI, 2000
[45] Pan J. X., Zheng S. T., Yang G. Y., Crystal Growth & Design, 2005, 5(1), 237

Hydrothermal Synthesis of a New Zinc Phosphite (C₅H₇N₂)₂·[Zn₃(HPO₃)₄] with Intersecting 8- and 12-Ring Channels

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	WANG Yan, XI Peng, SHU Dengkun, MENG Shuang, LIU Kai, WANG Xiaoqing, CHENG Bowen. Preparation and Properties of Electrospun Sheath-core Modified-PMMA Nanofibers with Photoluminescence and Photochromic Functions [J]. Chemical Research in Chinese Universities, 2021, 37(3): 549-557.
[2]	ZHANG Tianning, ZHANG Kenan, CHEN Xiren, WANG Shuxia, ZHANG Rongjun, SHAO Jun, CHEN Xin, DAI Ning. Temperature-dependent Photoluminescence of Silicon Nanocrystals Embedded in SiO₂ Matrix [J]. Chemical Research in Chinese Universities, 2018, 34(4): 513-516.
[3]	ZHANG Jiaqi, WANG Shan, YUAN Long, HOU Changmin. Hydrothermal Synthesis and Magnetic Properties ofSmCr_0.5M_0.5O₃(M=Fe and Mn) Micro-plates [J]. Chemical Research in Chinese Universities, 2018, 34(1): 1-7.
[4]	CHEN Yanli, DONG Xinglong, ZHANG Zhenyu, FENG Lai. Multicolor Photoluminescence in ITQ-16 Zeolite Film [J]. Chemical Research in Chinese Universities, 2016, 32(5): 713-718.
[5]	WU Xiaomei, LIU Guocheng, WANG Xiuli, SHAO Jiyan, LIN Hongyan, WANG Xiang. Three Ni(Ⅱ) Coordination Polymers with Various Architectures Based on Asymmetric Bis-pyridyl-amide and Polycarboxylates: Syntheses, Structures and Properties [J]. Chemical Research in Chinese Universities, 2016, 32(5): 719-724.
[6]	ZHANG Zaichao, HU Gonghao, XU Yan. Hydrothermal Synthesis, Structure and Properties of a New Phosphomolybdate Based on Novel [Co(H₂O)₄(HP₂Mo₅O₂₃)]^8- Anions and [H₈(H₂O)₁₆]⁸⁺ Water Cluster Cations [J]. Chemical Research in Chinese Universities, 2016, 32(3): 329-333.
[7]	WANG Xi, HAN Bin, GAO Yan, WANG Li, BAI Ming. HEDP-capped Terbium Orthophosphate Nanoparticles as Sensitive Luminescent Probes for the Detection of Pb²⁺ Ions [J]. Chemical Research in Chinese Universities, 2016, 32(3): 325-328.
[8]	DONG Weili, ZHANG Xiyan, SHI Hui, WANG Nengli, ZHANG Wenmin, LI Liang, XUE Qingxue. Preparation and Luminescence Properties of Color-tunable Single-phased LaPO₄: Eu³⁺/Tb³⁺ Phosphors [J]. Chemical Research in Chinese Universities, 2016, 32(2): 248-252.
[9]	HUANG Yantao, LAN Yuwei, YI Qilei, HUANG Hualin, WANG Yilin, LU Jianping. Microwave-assisted Synthesis of CdTe Quantum Dots Using 3-Mercaptopropionic Acid as Both a Reducing Agent and a Stabilizer [J]. Chemical Research in Chinese Universities, 2016, 32(1): 16-19.
[10]	ZHANG Guochun, QIAO Chengfang, LIANG Jiehui, WEI Qing, XIA Zhengqiang, CHEN Sanping. Hydrothermal Synthesis, Structure and Property of Transition Metal(Mn, Zn, Cd or Pb) Coordination Frameworks Using Quinoline-8-oxy-acetate Acid and Dicarboxylic Acid as Ligands [J]. Chemical Research in Chinese Universities, 2015, 31(4): 489-497.
[11]	FANG Weihui, YANG Guoyu. A Series of Lanthanide Coordination Polymers Constructed from 4-Pyridin-4-ylbenzoate [J]. Chemical Research in Chinese Universities, 2015, 31(2): 187-191.
[12]	Mouna SMIDA, Hager LITAIEM, Mohamed DAMMAK, Santiago GARCIA-GRANDA. Structure, Thermal Behavior and Characterization of a New Hybrid Iron Fluoride FeF₄(2,2'-bipyridine)(H₂O)₂ [J]. Chemical Research in Chinese Universities, 2015, 31(1): 16-20.
[13]	LIU Yabing, DUAN Weijie, CUI Xiaobing, XU Jiqing. Hydrothermal Syntheses and Characterization of Two 1D Chain Complexes and Tetra-capped Keggin Clusters [J]. Chemical Research in Chinese Universities, 2015, 31(1): 4-8.
[14]	GU Yipeng, SHEN Hongzhi, LI Liang, LIU Wenqiang, WANG Wenquan, XU Dapeng. Electrospinning Synthesis and Photoluminescence Properties of SnO₂:xEu³⁺ Nanofibers [J]. Chemical Research in Chinese Universities, 2014, 30(6): 879-884.
[15]	WANG Xiuli, GONG Chunhua, QU Yun, LIU Guocheng, ZHANG Juwen. Syntheses, Structures and Properties of Three Transition Metal Coordination Polymers Based on Semi-rigid 3-Pyridylnicotinamide and S/N-Containing Dicarboxylate Mixed Ligands [J]. Chemical Research in Chinese Universities, 2014, 30(5): 709-714.