Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (4): 527-529.doi: 10.1007/s40242-016-6058-x

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Ionothermal Synthesis and Characterization of Two Polyoxometalate-based Supramolecules

GAI Beibei, HE Hui, ZHAO Yanhui, MAO Zhu, FU Hai   

  1. School of Chemistry and Life Science, Changchun University of Technology, Changchun 130012, P. R. China
  • Received:2016-02-19 Revised:2016-03-28 Online:2016-08-01 Published:2016-04-20
  • Contact: FU Hai E-mail:mr.fuhai@163.com
  • Supported by:

    Supported by the National Natural Science Foundation of China(No.21301019), the Youth Foundation of Science and Technology Department of Jilin Province, China(No.20130522129JH), the National Science Foundation for Post-doctoral Scientists of China(No.2013M530135) and the Project of the Technology Department of Jilin Province, China(No.ZDZH2011003).

Abstract:

Two novel 3D supramolecular architectures with hexamolybdate and phosphotungstate anions were synthesized under ionothermal conditions. The structures were named as[CuI(L1)2]2L2[Mo6O19](1) and[CuI(L3)2]2.5· H0.5[PW12O40]·H2O(2)(L1=2,2'-bipyridine, L2=4,4'-bipyridine, L3=2,2'-biimidazole) and characterized via Fourier transform infrared spectroscopy(FTIR) and FT-Raman spectroscopy analyses. Single-crystal X-ray diffraction analysis revealed that the two compounds crystallized in the space group P and were constructed through hydrogen bonding.

Key words: Ionothermal, Polyoxometalate, Supramolecule