Synthesis and Structure of Ion-pairComplex [Mo(dtc)4][Sm(dtc)4]

Abstract

Abstract: Tetra (N, N-diethyldithiocarbamates) Samarium (Ⅲ)tetra (N, N-di-ethyldithiocarbamates)Molybdenum (V)([Mo(dtc)₄][Sm(dtc)₄])was synthesizedby the reaction of [Mo(dtc)₄]Cl and Na[Sm(dtc)₄] in miethanol.The crystal struc-ture was determined using X-ray diffraction methods.The compound crystallizes inthe triclinic space group P1 with the lattice parameters: a =1.1557(4) nm, b=1.5253(3) nm, c=1.8670 (6) nm and a=97.001 (20)°, β=94.506(24)°, γ=93.419(20)°,Z=2.The final R=0.059.The spectroscopic and XPSstudies werecarried out.

Key words: Crystal structure, Molybdenum(Ⅲ), Samarium(Ⅴ)

SUN Chun-ting, ZHU Ya-bin, LIU Xiao-xun, YI Shuzhen, LI Li, ZHENG Xiao-feng, WANG Yue. Synthesis and Structure of Ion-pairComplex [Mo(dtc)₄][Sm(dtc)₄][J]. Chemical Research in Chinese Universities, 1994, 10(3): 236-239.

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Synthesis and Structure of Ion-pairComplex [Mo(dtc)₄][Sm(dtc)₄]

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