Conversion of CO2 to Multi-carbon Compounds over a CoCO3 Supported Ru-Pt Catalyst Under Mild Conditions

doi:10.1007/s40242-021-1382-1

Chemical Research in Chinese Universities ›› 2022, Vol. 38 ›› Issue (1): 223-228.doi: 10.1007/s40242-021-1382-1

• Articles • Previous Articles Next Articles

Conversion of CO₂ to Multi-carbon Compounds over a CoCO₃ Supported Ru-Pt Catalyst Under Mild Conditions

HUANG Jin¹, CAI Yichen¹, YU Yulv¹, WANG Yuan^1,2

1. Beijing National Laboratory for Molecular Sciences, State Key Lab. for Structural Chemistry of Unstable and Stable Species, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China;
2. Sunan Institute for Molecular Engineering, Peking University, Changshu 215500, P. R. China

Received:2021-09-23 Revised:2021-10-25 Online:2022-02-01 Published:2021-10-25
Contact: WANG Yuan E-mail:wangy@pku.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (Nos.91961103, 21821004) and the Beijing National Laboratory for Molecular Sciences, China(No.BNLMS-CXXM-202001).

Abstract

Abstract: The catalytic hydrogenation of CO₂ to multi-carbon compounds under mild conditions would not only provide value-added products, but also benefit for the reduction of CO₂ emission if hydrogen derives from renewable energy sources. Herein, we report CoCO₃ supported Ru and Pt nano-particles, which could catalyze hydrogenation of CO₂ to produce higher hydrocarbons(C₂-C₂₆) and higher alcohols(C₂OH-C₆OH) at low temperatures of 80-130℃. The selectivity for C₂₊ compounds reached 81.1% at 80℃, which was the highest value reported so far. This work provides a promising catalyst for highly selective converting CO₂ and H₂ to C₂₊ compounds at low temperatures.

Key words: Heterogeneous catalyst, Carbon dioxide, Hydrogenation reaction, Cobalt carbonate, Multi-carbon compound

HUANG Jin, CAI Yichen, YU Yulv, WANG Yuan. Conversion of CO₂ to Multi-carbon Compounds over a CoCO₃ Supported Ru-Pt Catalyst Under Mild Conditions[J]. Chemical Research in Chinese Universities, 2022, 38(1): 223-228.

References

[1] Wu T. W., Hu A. X., Gao F., Zhang J., Meehl G. A., NPJ Clim. Atmos. Sci., 2019, 2, 18
[2] Hurd C. L., Lenton A., Tilbrook B., Boyd P. W., Nat. Clim. Change, 2018, 8, 686
[3] Ra E. C., Kim K. Y., Kim E. H., Lee H., An K., Lee J. S., ACS Catal., 2020, 10, 11318
[4] Tarasov A. L., Isaeva V. I., Tkachenko O. P., Chernyshev V. V., Kustov L. M., Fuel Process. Technol., 2018, 176, 101
[5] He Z. H., Cui M., Qian Q. L., Zhang J. J., Liu H. Z., Han B. X., Proc. Natl. Acad. Sci. USA, 2019, 116, 12654
[6] Owen R. E., Byrne J. P., Mattia D., Plucinski P., Pascu S. I., Jones M. D., Chem. Commun., 2013, 49, 11683
[7] Shi Z. B., Yang H. Y., Gao P., Chen X. Q., Liu H. J., Zhong L. S., Wang H., Wei W., Sun Y. H., Chinese. J. Catal., 2018, 39, 1294
[8] Li Z. L., Wang J. J., Qu Y. Z., Liu H. L., Tang C. Z., Miao S., Feng Z. C., An H. Y., Li C., ACS. Catal., 2017, 7, 8544
[9] Zhou C., Shi J. Q., Zhou W., Cheng K., Zhang Q. H., Kang J. C., Wang Y., ACS. Catal., 2020, 10, 302
[10] Ni Y. M., Chen Z. Y., Fu Y., Liu Y., Zhu W. L., Liu Z. M., Nat. Commun., 2018, 9, 3457
[11] Wang Y., Tan L., Tan M. H., Zhang P. P., Fang Y., Yoneyama Y., Yang G. H., Tsubaki N., ACS Catal., 2019, 9, 895
[12] Yu Y. L., Huang J., Wang Y., Sustainable Energy & Fuels, 2020, 4, 96
[13] Wang Y., Ren J. W., Deng K., Gui L. L., Tang Y. Q., Chem. Mat., 2000, 12, 1622
[14] He B. L., Chen Y. X., Liu H. F., Liu Y., J. Nanosci. Nanotechno., 2005, 5, 266
[15] Chen L. F., Yu Y. L., Kuwa M., Cheng T., Liu Y., Murakami H., Harada M., Wang Y., Acta Phys. -Chim. Sin., 2020, 36, 1907008
[16] Cong H. P., Yu S. H., Cryst. Growth Des., 2009, 9, 210
[17] Ra E. C., Kim K. Y., Kim E. H., Lee H., An K., Lee J. S., ACS Catal., 2020, 10, 11318
[18] Sun Z. Y., Liu Z. M., Han B. X., Wang Y., Du J. M., Xie Z. L., Han G. J., Adv. Mater., 2005, 17, 928
[19] Yu Y. L., Huang J., Wang Y., ChemCatChem, 2018, 10, 4863
[20] Yang J., Cheng H. F., Frost R. L., Spectrochim. Acta. A Mol. Biomol. Spectrosc., 2011, 78, 420

Conversion of CO₂ to Multi-carbon Compounds over a CoCO₃ Supported Ru-Pt Catalyst Under Mild Conditions

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	MA Yanfu, WANG Liwei, LIU Jian. Single Atom Catalysts in Liquid Phase Selective Hydrogenations [J]. Chemical Research in Chinese Universities, 2022, 38(5): 1163-1171.
[2]	WANG Tianxiong, MU Zhenjie, DING Xuesong and HAN Baohang. Functionalized COFs with Quaternary Phosphonium Salt for Versatilely Catalyzing Chemical Transformations of CO₂ [J]. Chemical Research in Chinese Universities, 2022, 38(2): 446-455.
[3]	XUE Jingqi, LI Feng, ZHAI Xue, LI Dan, GUO Lijun, LI Cuiqin. Multiwalled Carbon Nanotubes Modified with Silylated-salicylaldimine Co(II) and Pd(II) Complexes as Precatalysts in Ethylene Oligomerization [J]. Chemical Research in Chinese Universities, 2022, 38(2): 552-561.
[4]	LI Jing-Hong, XIE Yi, ZHOU Mu-Yang, LIN Rui-Biao, CHEN Xiao-Ming. Microporous Zinc Formate for Efficient Separation of Acetylene over Carbon Dioxide [J]. Chemical Research in Chinese Universities, 2022, 38(1): 87-91.
[5]	FU Xinliang, ZHU Aonan, CHEN Xiaojie, ZHANG Shifu, WANG Mei, YUAN Mingjian. Stabilization of Cu/Ni Alloy Nanoparticles with Graphdiyne Enabling Efficient CO₂ Reduction [J]. Chemical Research in Chinese Universities, 2021, 37(6): 1328-1333.
[6]	YANG Chan, CHAI Jiaxin, WANG Zhe, XING Yonglei, PENG Juan, YAN Qingyu. Recent Progress on Bismuth-based Nanomaterials for Electrocatalytic Carbon Dioxide Reduction [J]. Chemical Research in Chinese Universities, 2020, 36(3): 410-419.
[7]	HOU Junying, HAO Jianjun, WANG Yaya, LIU Jingchun. Synthesis of Cu^Ⅱ/ZIF-8 Metal-organic Framework Catalyst and Its Application in the Aerobic Oxidation of Alcohols [J]. Chemical Research in Chinese Universities, 2019, 35(5): 860-865.
[8]	ZHANG Yanmei, ZHANG Fan, ZHANG Xiang, XU Yingmei, QI Xiaohui, QUAN Chunshan. Assembly and Post-modification of Fe₃O₄@MIL-100(Fe) for Knoevenagel Condensation [J]. Chemical Research in Chinese Universities, 2018, 34(4): 655-660.
[9]	MA Jun, LAN Yang, MAO Hui, LIAO Yang, ZHAO Shilin. Preparation of Pt/γ-Al₂O₃-C Heterogeneous Catalyst for Highly Selective Hydrogenation of Cinnamaldehyde Towards Cinnamyl Alcohol [J]. Chemical Research in Chinese Universities, 2017, 33(4): 660-665.
[10]	DONG Shujun, WANG Lin, LI Qiushi, CHEN Xuesi, LIU Shujie, ZHOU Yanmin. Poly (L-lactide)-grafted Bioglass/Poly (lactide-co-glycolide) Scaffolds with Supercritical CO₂ Foaming Reprocessing for Bone Tissue Engineering [J]. Chemical Research in Chinese Universities, 2017, 33(3): 499-506.
[11]	LIU Li, LIN Maohai, LIU Zhongbo, SUN Honggang, ZHAO Xian. Density Functional Theory Study of CO₂ and H₂O Adsorption on a Monoclinic WO₃(001) Surface [J]. Chemical Research in Chinese Universities, 2017, 33(2): 255-260.
[12]	BEN Shunge, YUAN Fulong, ZHU Yujun. Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol [J]. Chemical Research in Chinese Universities, 2016, 32(6): 1005-1009.
[13]	LIU Jun, LAN Lixin, WU Chao, LI Rong, LIU Xuanyan. Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature [J]. Chemical Research in Chinese Universities, 2016, 32(2): 272-277.
[14]	ZHU Guo-wei, CHEN Xiao-bo, JIANG Hong, HUANG Jian, WANG Run-wei, QIU Shi-lun. Synthesis and Characterization of TS-1 with Aid of Supercritical CO₂ [J]. Chemical Research in Chinese Universities, 2013, 29(6): 1036-1039.
[15]	XU Dong, ZHANG Jun, LI Gang, XIAO Penny, ZHAI Yu-chun. Separation of H₂O/CO₂ Mixtures with Layered Adsorption Method for Greenhouse Gas Control [J]. Chemical Research in Chinese Universities, 2012, 28(1): 129-132.