Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature

doi:10.1007/s40242-016-5331-3

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (2): 272-277.doi: 10.1007/s40242-016-5331-3

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Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature

LIU Jun, LAN Lixin, WU Chao, LI Rong, LIU Xuanyan

Department of Pharmaceutical and Biological Engineering, Hunan Chemical Vocational Technology College, Zhuzhou 412004, P. R. China

Received:2015-08-17 Revised:2015-11-18 Online:2016-04-01 Published:2015-12-14
Contact: LIU Jun E-mail:151283329@qq.com
Supported by:
Supported by the Programs Foundation of Scientific Research of Education Department of Hunan Province, China (Nos.14C0381, 15C0464).

Abstract

Abstract:

Agglomerated Pd catalysts with the nano-porous structure were simply prepared by one-step reduction reaction without using any stabilizer. The Pd catalysts show a high catalytic activity for the decomposition of formic acid at room temperature. Among all the Pd catalysts tested, the Pd_Mg catalyst exhibits the highest catalytic activity. Moreover, the breakthrough of the advanced catalysts is that the above agglomerated Pd catalysts can be easily separated from the liquid system to control the catalytic reaction at any time, which may further promote the practical application of formic acid as a H₂ storage material.

Key words: Hydrogen energy, Heterogeneous catalyst, Formic acid decomposition, Pd catalyst, Nano-porous structure

LIU Jun, LAN Lixin, WU Chao, LI Rong, LIU Xuanyan. Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature[J]. Chemical Research in Chinese Universities, 2016, 32(2): 272-277.

References

[1] Winter C. J., Int. J. Hydrogen Energy, 2009, 34, S1
[2] Amoo L. M., Fagbenle R. L., Int. J. Hydrogen Energy, 2014, 39, 12409
[3] Albert B., Björn L., Henrik J., Matthias B., Chem. Sus. Chem., 2008, 1, 751
[4] Björn L., Albert B., Henrik J., Matthias B., Angew. Chem. Int. Ed., 2008, 47, 3962
[5] Henrik J., Albert B., Francesca C., Björn L., James R. N., Serafino G., Matthias B., Tetrahedron Lett., 2009, 50, 1603
[6] Björn L., Albert B., Henrik J., James R. N., Wolfgang B., Matthias B., Chem. Commun., 2009, (28), 4185
[7] Céline F., Paul J. D., Gábor L., Angew. Chem. Int. Ed., 2008, 47, 3966
[8] Céline F., Ning Y., Paul J. D., Gábor L., Chem. Eur. J., 2009, 15, 3752
[9] Miklos C., Alain G., Robert M., Ralf H., Prakash G. K. S., George A. O., Chem. Sus. Chem., 2011, 4, 1241
[10] Karaked T., Li T., Simon J., Chun W. A. C., Kai M. K. Y., Paul A. J. B., Emmanuelle A. M., Georg S. D. W., Shik C. E. T., Nat. Nanotech., 2011, 6, 302
[11] Zhou X. C., Huang Y. J., Xing W., Liu C. P., Liao J. H., Lu T. H., Chem. Commun., 2008, (30), 3540
[12] Zhou X. Z., Huang Y. J., Liu C. P., Liao J. H., Lu T. H., Xing W., Chem. Sus. Chem., 2010, 3, 1379
[13] Ping Y., Yan J. M., Wang Z. L., Wang H. L., Jiang Q., J. Mater. Chem. A, 2013, 1, 12188
[14] Dai H. M., Cao N., Yang L., Su J., Luo W., Cheng G. Z., J. Mater. Chem. A, 2014, 2, 11060
[15] Metin O., Sun X., Sun S., Nanoscale, 2013, 5, 910
[16] Kohsuke M., Masahiro D., Hiromi Y., ACS Catal., 2013, 3, 1114
[17] Yang L., Hua X., Sun J., Luo W., Chen S. L., Cheng G. Z., Appl. Catal. B, 2015, 168, 423
[18] Kaustab M., Debaleena B., Subrata D., Int. J. Hydrogen Energy, 2015, 40, 4786
[19] Dai H. G., Cao N., Yang L., Su J., Luo W., Cheng G. Z., J. Mater. Chem. A, 2014, 2, 11060
[20] Ahmet B., Mehmet Y., Yasar K., Zafer S., Hilal K., Murat K., Mehmet G., Emrah O., Mehmet Z., ACS Catal., 2015, 5, 6099
[21] Masashi H., Hisahiro E., Takeshi D., Masaharu T., J. Mater. Chem. A, 2015, 3, 4453
[22] Gazsi A., Bánsági T., Solymosi F., J. Phys. Chem. C, 2011, 115, 15459
[23] Manuel O., Enrique I., Angew. Chem. Int. Ed., 2009, 48, 4800
[24] Mahendra Y., Tomoki A., Nobuko T., Xu Q., J. Mater. Chem., 2012, 22, 12582
[25] Bi Q. Y., Du X. L, Liu Y. M., Cao Y., He H. Y., Fan K. N., J. Am. Chem. Soc., 2012, 134, 8926
[26] Wang Z. L., Yan J. M., Wang H. L., Ping Y., Jiang Q., Sci. Rep., 2012, 2, 598
[27] Hu C. Q., Ting S. W., Jenkin T., Chan K. Y., Int. J. Hydrogen Energy, 2012, 37, 6372
[28] Wang Z. L., Yan J. W., Wang H. L., Ping Y., Qing J., J. Mater. Chem. A, 2013, 1, 12721
[29] Yu W. Y., Mullen G. M., Flaherty D. W., Mullins C. B., J. Am. Chem. Soc., 2014, 136, 11070
[30] Wu S., Yang F., Wang H., Chen R., Sun P., Chen T. H., Chem. Commun., 2015, 51, 10887
[31] Wu S., Yang F., Sun P., Chen T. H., RSC Adv., 2014, 4, 44500
[32] Wang X., Qi G. W., Tan C. H., Li Y. P., Guo J., Pang X. J., Zhang S. Y., Int. J. Hydrogen Energy, 2014, 39, 837
[33] Hu L., Zheng B., Lai Z. P., Huang K. W., Int. J. Hydrogen Energy, 2014, 39, 20031
[34] Hu C. Q., Ting S. W., Chan K. Y., Huang W., Int. J. Hydrogen Energy, 2013, 38, 8720
[35] Wang Z. L., Ping Y., Yan J. M., Wang H. L., Jiang Q., Int. J. Hydrogen Energy, 2014, 39, 4850
[36] Mehmet Y., Ahmet B. M. Z., Murat K., Appl. Catal. B:Environ., 2014, 160, 514
[37] Zhang H., Metin O., Su D., Sun S., Angew. Chem., Int. Ed., 2013, 52, 3681
[38] Liu J., Cao L., Xia Y., Huang W., Li Z. L., Int. J. Electrochem. Sci., 2013, 8, 9435
[39] ?ukaszewski M., Czerwiński A., Thin Solid Films, 2010, 518, 3680
[40] Cheng N. C., Lv H. F., Wang W., Mu S. C., Pan M., Frank M., J. Power Sources, 2010, 195, 7246

Agglomerated Pd Catalysts and Their Applications in Hydrogen Production from Formic Acid Decomposition at Room Temperature

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