Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO2 Hydrogenation to Methanol

doi:10.1007/s40242-016-6130-6

Abstract

Abstract:

A series of 50%CuO-25%ZnO-25%Al(Zr) oxide catalysts was synthesized by a reverse co-precipitation method and characterized by XRD, N₂ adsorption-desorption, H₂-TPR, H₂-TPD and CO₂-TPD, and used as catalyst for CO₂ hydrogenation to methanol under mild conditions(200-260℃ and 1-3 MPa). Consequently, H₂-TPR exhibited that the dispersed CuO species increased with the zirconium content, while the H₂-TPD showed that small amount of zirconia can increase the H₂ desorption amount. As a result, Cat-2 and Cat-3 exhibited an enhanced H₂-spillover effect, the most H₂ desorption amount, which showed an optimum activity of about 7% methanol yield.

Key words: Carbon dioxide, Reverse co-precipitation, Methanol, Catalytic hydrogenation, Copper based catalyst

BEN Shunge, YUAN Fulong, ZHU Yujun. Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol[J]. Chemical Research in Chinese Universities, 2016, 32(6): 1005-1009.

References

[1] Chen Q., Lv M., Tang Z., Wang H., Wei W., Sun Y., J. CO₂ Util., 2016, 14, 1
[2] Wang W., Wang S., Ma X., Gong J., Chem. Soc. Rev., 2011, 40(7), 3703
[3] Li L., Zhao N., Wei W., Sun Y., Fuel, 2013, 108, 112
[4] Munshi P., Main A. D., Linehan J. C., Tai C. C., Jessop P. G., J. Am. Chem. Soc., 2002, 124(27), 7963
[5] Bai H. P., Zheng Y. P., Li P. P., Zhang A. B., Chem. Res. Chinese Universities, 2015, 31(3), 488
[6] Gao P., Li F., Xiao F., Zhao N., Wei W., Zhong L., Sun Y., Catal. Today, 2012, 194(1), 9
[7] Raudaskoski R., Niemelä M. V., Keiski R. L., Top. Catal., 2007, 45(1-4), 57
[8] Gao P., Li F., Zhan H., Zhao N., Xiao F., Wei W., Zhong L., Wang H., Sun Y., J. Catal., 2013, 298, 51
[9] Arena F., Mezzatesta G., Zafarana G., Trunfio G., Frusteri F., Spadaro L., J. Catal., 2013, 300, 141
[10] Grabowski R., S?oczyński J., ?liwa M., Mucha D., Socha R. P., Lachowska M., Skrzypek J., ACS Catal., 2011, 1(4), 266
[11] Kwak J. H., Kovarik L., Szanyi J., ACS Catal., 2013, 3(11), 2449
[12] Zhang R., Liu H., Wang B., Ling L., Appl. Catal. B, 2012, 126, 108
[13] Liang X. L., Dong X., Lin G. D., Zhang H. B., Appl. Catal. B, 2009, 88(3/4), 315
[14] Karelovic A., Bargibant A., Fernández C., Ruiz P., Catal. Today, 2012, 197(1), 109
[15] Ernst K. H., Schlatterbeck D., Christmann K., Phys. Chem. Chem. Phys., 1999, 1(17), 4105
[16] Li Z. X., Na W., Wang H., Gao W. G., Chem. J. Chinese Universities, 2014, 35(12), 2616
[17] Liu R., Zha F., Yang A. M., Chang Y., Chem. J. Chinese Universities, 2016, 37(5), 964
[18] Zhang Y. N., Li J. L., Huang X. R., Chem. J. Chinese Universities, 2016, 37(3), 534
[19] Shishido T., Yamamoto M., Li D., Tian Y., Morioka H., Honda M., Sano T., Takehira K., Appl. Catal. A, 2006, 303(1), 62
[20] Jones S. D., Neal L. M., Hagelin-Weaver H. E., Appl. Catal. B, 2008, 84(3/4), 631
[21] Baltes C., Vukojevic S., Schuth F., J. Catal., 2008, 258(2), 334
[22] Wang D., Tao F., Zhao H., Song H., Chou L., Chinese J. Catal., 2011, 32(9/10), 1452
[23] Ladera R., Pérez-Alonso F. J., González-Carballo J. M., Ojeda M., Rojas S., Fierro J. L. G., Appl. Catal. B, 2013, 142/143, 241
[24] Zhuang H. D., Bai S. F., Liu X. M., Yan Z. F., J. Fuel Chem. Technol., 2010, 38(4), 462
[25] Collins S. E., Chiavassa D. L., Bonivardi A. L., Baltanás M. A., Catal. Lett., 2005, 103(1/2), 83
[26] Guo X., Mao D., Lu G., Wang S., Wu G., Catal. Commun., 2011, 12(12), 1095
[27] Wu D. L., Jiang W., Liu X. Q., Qiu N. X., Xue Y., Chem. Res. Chinese Universities, 2016, 32(1), 118
[28] Zhao Y. F., Yang Y., Mims C., Peden C. H. F., Li J., Mei D., J. Catal., 2011, 281(2), 199
[29] Medford A. J., Sehested J., Rossmeisl J., Chorkendorff I., Studt F., Nørskov J. K., Moses P. G., J. Catal., 2014, 309, 397
[30] Grabow L. C., Mavrikakis M., ACS Catal., 2011, 1(4), 365
[31] Wang D., Zhao J., Song H., Chou L., J. Nat. Gas Chem., 2011, 20(6), 629
[32] Baltes C., Vukojevic S., Schuth F., J. Catal., 2008, 258, 334
[33] Behrens M., Kasatkin I., Kühl S., Weinberg G., Chem. Mater., 2010, 22(2), 386
[34] Arena F., Italiano G., Barbera K., Bordiga S., Bonura G., Spadaro L., Frusteri F., Appl. Catal. A, 2008, 350(1), 16
[35] An X., Li J., Zuo Y., Zhang Q., Wang D., Wang J., Catal. Lett., 2007, 118(3/4), 264
[36] Li C., Yuan X., Fujimoto K., Appl. Catal. A, 2014, 469, 306
[37] Kong L. Z., Wang Q., Xu L., Yan Y. S., Li H. M., Yang X. G., Chem. J. Chinese Universities, 2015, 36(7), 1372
[38] Wambach J., Baiker A., Wokaun A., Phys. Chem. Chem. Phys., 1999, 1(22), 5071
[39] Guo X., Mao D., Wang S., Wu G., Lu G., Catal. Commun., 2009, 10(13), 1661
[40] Arena F., Mezzatesta G., Zafarana G., Trunfio G., Frusteri F., Spadaro L., Catal. Today, 2013, 210, 39
[41] Jia L., Gao J., Fang W., Li Q., J. Rare Earth., 2010, 28(5), 747
[42] Zhan H., Li F., Gao P., Zhao N., Xiao F., Wei W., Zhong L., Sun Y., J. Power Sources, 2014, 251, 113

Effect of Zr Addition on Catalytic Performance of Cu-Zn-Al Oxides for CO₂ Hydrogenation to Methanol

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