Functionalized COFs with Quaternary Phosphonium Salt for Versatilely Catalyzing Chemical Transformations of CO2

doi:10.1007/s40242-022-1495-1

Abstract

Abstract: Currently, it encounters great challenges to accomplish catalyzing various kinds of carbon dioxide(CO₂) conversion reactions efficiently with single catalyst, let alone control the interplay among catalytic efficiency and selectivity evenly. Here, we prepared a functional covalent organic framework, [PTPP]_X_%-TD-COF[PTPP=3-bromopropyltriphenylphosphonium; TD=1,3,5-tri(4-aminophenyl)benzene-1,4-diformylbenzene], by immobilizing the quaternary phosphonium salt onto the skeleton of COFs through a post-synthesis strategy for versatilely catalyzing reduction of CO₂ and CO₂ fixation on epoxide and aziridine facilely. With the typical features of COFs(such as porosity and ordered structure) and catalytic activity of the quaternary phosphonium salt, [PTPP]_X_%-TD-COF possesses an intensely synergistic effect for catalyzing the chemical transformations of CO₂. Noteworthily, the quaternary phosphonium salt functionalized COFs catalyze the CO₂ reduction reaction with amine and phenylsilane to produce formylated and methylated products under gentle reaction conditions with high selectivity and efficiency. Furthermore, [PTPP]_X_%-TD-COF shows high catalytic ability in CO₂ chemical fixation reactions.

Key words: Covalent organic framework, Quaternary phosphonium salt, Heterogeneous catalysis, Carbon dioxide, Chemical transformation

WANG Tianxiong, MU Zhenjie, DING Xuesong and HAN Baohang. Functionalized COFs with Quaternary Phosphonium Salt for Versatilely Catalyzing Chemical Transformations of CO₂[J]. Chemical Research in Chinese Universities, 2022, 38(2): 446-455.

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Functionalized COFs with Quaternary Phosphonium Salt for Versatilely Catalyzing Chemical Transformations of CO₂

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