Synthesis of Magnetic Nickel Ferrite Microspheres and Their Microwave Absorbing Properties

doi:10.1007/s40242-016-5457-3

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (4): 678-681.doi: 10.1007/s40242-016-5457-3

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Synthesis of Magnetic Nickel Ferrite Microspheres and Their Microwave Absorbing Properties

JIAO Qingze^1,2, WANG Yanfeng¹, HAO Liang¹, LI Hansheng¹, ZHAO Yun¹

1. School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, P. R. China;
2. School of Chemical Engineering and Materials Science, Beijing Institute of Technology, Zhuhai, Zhuhai 519085, P. R. China

Received:2015-11-26 Revised:2016-03-02 Online:2016-08-01 Published:2016-04-20
Contact: ZHAO Yun E-mail:zhaoyun@bit.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21376029, 21071017).

Abstract

Abstract:

NiFe₂O₄ microspheres were synthesized using a solvothermal method. The morphologies and structures of NiFe₂O₄ micropheres were characterized via a field emission scanning electron microscope(FESEM), a transmission electron microscope(TEM) and an X-ray diffractometer(XRD). The NiFe₂O₄ microspheres were around 150-200 nm in diameter and assembled by nanoparticles. The magnetic and electromagnetic parameters were measured using a vibrating sample magnetometer and a vector network analyzer, respectively. The obtained products exhibited a saturation magnetization of 60.8 A·m²·kg^-1 at room temperature. A minimum reflection loss(RL) of -27.8 dB was observed at 9.2 GHz with a thickness of 3.5 mm, and the effective absorption frequency(RL<-10 dB) ranged from 8.2 GHz to 11.2 GHz, indicating the excellent microwave absorption performance of the NiFe₂O₄ microspheres in the X-band frequencies.

Key words: Nickel ferrite microsphere, Magnetic property, Microwave absorption property

JIAO Qingze, WANG Yanfeng, HAO Liang, LI Hansheng, ZHAO Yun. Synthesis of Magnetic Nickel Ferrite Microspheres and Their Microwave Absorbing Properties[J]. Chemical Research in Chinese Universities, 2016, 32(4): 678-681.

References

[1] Li D. S., Horikawa T., Liu J. R., Itoh M., Machida K., J. Alloys Compd., 2006, 408, 1429
[2] Qi X. S., Yang Y., Zhong W., Deng Y., Au C., Du Y. W., J. Solid State Chem., 2009, 182, 2691
[3] Tyagi S., Verma P., Baskey H. B., Agarwala R. C., Agarwala V., Shami T. C., Ceram. Int., 2012, 38, 4561
[4] Jauchem J. R., Ryan K. L., Freidagger M. R., Bioelectromagnetics, 2000, 21, 159
[5] Veyret B., Bouthet C., Deschaux P., Seze R. D., Geffard M., Joussot-Dubien J., Diraison M. L., Moreau J. M., Caristan A., Bioelectromagnetics, 1991, 12, 47
[6] Ritcher E., Berman T., Ben-Michael E., Laster R., Weatin J. B., Int. J. Occup. Environ. Health, 2000, 6, 187
[7] Hou X. Y., Feng J., Liu X. H., Zhang M. L., Chem. Res. Chinese Universities, 2011, 27(4), 543
[8] Zou Z., Xuan A. G., Yan Z. G., Wu Y. X., Li N., Chem. Eng. Sci., 2010, 65, 160
[9] Feng J., Hou X., Chen T., Liu S., Fan Z., Ren Y., Lü Y., Chem. Res. Chinese Universities, 2015, 31(5), 885
[10] Lima U. R., Nasar M. C., Nasar R. S., Rezende M. C., Araujo J. H., Oliveira J. F., Mater. Sci. Eng. B: Adv., 2008, 151, 238
[11] Huang X. G., Zhang J., Xiao S. R., Chen G. S., J. Am. Ceram. Soc., 2014, 97, 1363
[12] Fu M., Jiao, Q. Z., Zhao Y., Mater. Charact., 2013, 86, 303
[13] Fu M., Jiao Q. Z., Zhao Y., Li H. S., J. Mater. Chem. A, 2014, 2, 735
[14] Ji R. L., Cao C. B., Chen Z., Zhai H. Z., Bai J., J. Mater. Chem. C, 2014, 2, 5994
[15] Sunny V., Kurian P., Mohanan P., Joy P. A., Anantharaman M. R., J. Alloys Compd., 2010, 489, 297
[16] Khairy M., Synthetic Met., 2014, 189, 34
[17] Gu X., Zhu W. M., Jia C. J., Zhao R., Schmidt W., Wang Y. Q., Chem. Commun., 2011, 47, 5337
[18] Zhu W. M., Wang L., Zhao R., Ren J. W., Lu G. Z., Wang Y. Q., Nanoscale, 2011, 3, 2862
[19] Caizer C., Mater. Sci. Eng. B: Adv., 2003, 100, 63
[20] Chappert J., Frankel R. B., Phys. Rev. Lett., 1967, 19, 570
[21] Sivakumar P., Ramesh R., Ramanand A., Ponnusamy S., Muthamizhchelvan C., Mater. Lett., 2011, 65, 1438
[22] Jiang J., Yang Y. M., Mater. Lett., 2007, 61, 4276
[23] Yi H. B., Wen F. S., Qiao L., Li F. S., J. Appl. Phys., 2009, 106, 103922
[24] Wu M. Z., Zhang Y. D., Hui S., Xiao T. D., Ge S. H., Hines W. A., Budnick J. T., Taylor G. W., Appl. Phys. Lett., 2002, 80, 4404
[25] Zhang X. F., Dong X. L., Huang H., Liu Y. Y., Lv B., Lei J. P., Choi C. J., J. Phys. D: Appl. Phys., 2007, 40, 5383

Synthesis of Magnetic Nickel Ferrite Microspheres and Their Microwave Absorbing Properties

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