Shape-controlled Synthesis of Fe3O4 Nanocrystals with Incontinuous Multicavities

doi:10.1007/s40242-016-5383-4

Abstract

Abstract:

In the solvothermal synthesis process, the effect of NaOH dosages of from 0.3 g to 4.0 g on the morphology evolution(from nanoparticles to octahedra) of Fe₃O₄ crystals was carefully investigated. Meanwhile, the growth process of Fe₃O₄ crystals at different reaction time was also investigated. Furthermore, it has been found that the particle size and crystallinity of Fe₃O₄ crystals can be controlled by the dosages of NaOH. In this paper, the increases of both the reaction time and the NaOH concentrations correspond to a minimization process of surface energy for Fe₃O₄ crystals. During the synthesis process, the addition of N₂H₄·H₂O and ethylene glycol in the magnetite not only facilitated the narrow distribution of particle size but also contributed to the formation of incontinuous multicavities with a diameter of about 5 nm.

Key words: Fe₃O₄ nanocrystal, Incontinuous multicavity, Magnetic property

ZHAN Conghong, CHENG Rongmin, FANG Beibei, ZHAO Lijun. Shape-controlled Synthesis of Fe₃O₄ Nanocrystals with Incontinuous Multicavities[J]. Chemical Research in Chinese Universities, 2016, 32(2): 159-164.

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Shape-controlled Synthesis of Fe₃O₄ Nanocrystals with Incontinuous Multicavities

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