Hydrothermal Synthesis, Structure and Property of Transition Metal(Mn, Zn, Cd or Pb) Coordination Frameworks Using Quinoline-8-oxy-acetate Acid and Dicarboxylic Acid as Ligands

doi:10.1007/s40242-015-5104-4

Abstract

Abstract:

Five transition metal coordination compounds, [Mn₂(8-qoac)₂(bdc)(H₂O)₄](1)(8-qoacH=quinoline-8-oxy- acetate acid, H₂bdc=benzene-1,4-dicarboxylic acid), [Zn₄(8-qoac)₄(bdc)₂]_n(2), {[Cd₂(8-qoac)₂(Hip)₂(H₂O)₂]· (H₂O)₄}_n(3)(H₂ip=benzene-1,3-dicarboxylic acid), [Pb₃(8-qoac)₂(bdc)_1.5(H₂O)Cl]_n(4) and [Zn₂(8-qoac)(8-ql)(bdc)]_n(5)(8-Hql=8-hydroxyquinoline), were synthesized by hydrothermal syntheses of metal salts with benzenedicarboxy- lic acid and 8-qoacH. Compound 1 possesses a discrete dimer bridged by bdc^2- ligand. Compound 2 presents a 2D layer network constructed from bdc^2- linkers and 1D infinite ribbons, in which Zn(II) centers are bridged by 8-qoac^- with a tetradentate binding mode. Compound 3 displays a 1D zigzag chain, with adjacent chains further connected via extensive O—H···O hydrogen bonds to generate a 3D supramolecular structure. Compound 4 shows a 3D framework containing trinuclear lead secondary building units and bdc^2- linkers, in which a new coordination mode of 8-qoac^- ligand is observed. In compound 5, Zn(II) ions are simultaneously bridged by 8-qoac^-, 8-ql^- and bdc^2- ligands to form tetranuclear zinc units, which are further interlinked by bdc^2- linkers to yield a 2D wave-like layer. Based on intraligand(IL)(π-π^*) fluorescent emission, compounds 1―5 possess strong purple fluorescent emissions. In addition, the thermal stabilities of compounds 1―5 were studied.

Key words: Coordination compound, Quinoline-8-oxy-acetate acid, Crystal structure, Photoluminescence property

ZHANG Guochun, QIAO Chengfang, LIANG Jiehui, WEI Qing, XIA Zhengqiang, CHEN Sanping. Hydrothermal Synthesis, Structure and Property of Transition Metal(Mn, Zn, Cd or Pb) Coordination Frameworks Using Quinoline-8-oxy-acetate Acid and Dicarboxylic Acid as Ligands[J]. Chemical Research in Chinese Universities, 2015, 31(4): 489-497.

References

[1] Kitagawa S., Kitaura R., Noro S., Angew. Chem. Int. Ed., 2004, 43, 2334
[2] Zheng Y. Z., Wei H.Y., Pan F., Wang Z. M., Chen Z. D., Gao S., Angew. Chem. Int. Ed., 2005, 44, 5841
[3] Eddaoudi M., Kim J., Rosi N., Vodak D., Wachter J., O'Keeffe M., Yaghi O. M., Science, 2002, 295, 469
[4] Zhang J. P., Zhang Y. B., Lin J. B., Chen X. M., Chem. Rev., 2012, 112, 1001
[5] Zheng Y. Z., Gao S., Sun H. L., Su G., Wang Z. M., Zhang S.W., Chem. Commun., 2004, 1906
[6] Liu C., Zhuo X., Zhang H., Liu X. H., Chem. J. Chinese Universities, 2014, 35(5), 928
[7] Wang Y. Y., Zhang Z., Sun Y. J., Li J. Y., Chem. J. Chinese Universities, 2014, 35(3), 449
[8] Müller I. M., Robson R., Angew. Chem. Int. Ed., 2000, 39, 4357
[9] Abrahams B. F., Jackson P. A., Robson R., Angew. Chem. Int. Ed., 1998, 37, 2656
[10] Park K. M., Moon S. T., Kang Y. J., Kim H. J., Seo J., Lee S. S., Inorg. Chem. Commun., 2006, 9, 671
[11] Benito-Garagorri D., Lackner-Warton W., Standfest-Hauser C. M., Mereiter K., Kirchner K., Inorg. Chim. Acta, 2010, 363, 3674
[12] Kalita D., Deka H., Samanta S. S., Guchait S., Baruah J. B., J. Mol. Struct., 2011, 990, 183
[13] Zheng Z. B., Wu R.T., Li J. K., Sun Y. F., J. Coord. Chem., 2008, 61, 2750
[14] Al-Mandhary M. R. A., Fitchett C. M., Steel P. J., Aust. J. Chem., 2006, 59, 307
[15] Man S. P., Benoit D. M., Buchaca E., Esan F., Motevalli M., Wilson J., Sullivan A., Inorg. Chem., 2006, 45, 5328
[16] Al-Mandhary M. R. A., Steel P. J., Eur. J. Inorg. Chem., 2004, 329
[17] Cheng X. N., Zhang W. X., Chen X. M., J. Am. Chem. Soc., 2007, 129, 15738
[18] Fan J., Wang Z. H., Huang Z. F., Yin X., Zhang W. G., Inorg. Chem. Commun., 2010, 13, 659
[19] Wang Y. H., Song R.F., Zhang F. Y., J. Mol. Struct., 2005, 752, 104
[20] Lin H. P., Zhou F., Li J., Zhang X. W., Zhang L., Jiang X. Y., Zhang Z. L., Zhang J. H., J. Phys. Chem. C, 2011, 115, 24341
[21] Qiao J., Wang L. D., Duan L., Li Y., Zhang D. Q., Qiu Y., Inorg. Chem., 2004, 43, 5096
[22] O'Keeffe M., Yaghi O. M., Chem. Rev., 2012, 112, 675
[23] Paz F. A. A., Khimyak Y. Z., Bond A. D., Rocha J., Klinowski J., Eur. J. Inorg. Chem., 2002, 2823
[24] Braun M. E., Steffek C. D., Kim J., Rasmussen P. G., Yaghi O. M., Chem. Commun., 2001, 2532
[25] Li X. J., Ma G. C., Xu X. H., J. Coord. Chem., 2013, 66, 3249
[26] Koelsch C. F., J. Am. Chem. Soc., 1931, 53, 304
[27] Sheldrick G. M., SHELXS-97, Program for X-ray Crystal Structure Determination, University of Göttingen, Göttingen, 1997
[28] Sheldrick G. M., SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Göttingen, 1997
[29] Wang J. J., Bao Q. L., Chen J. X., J. Coord. Chem., 2013, 66, 2578
[30] Nakamoto K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th Ed., John Wiley&Sons, New York, 1997, 62
[31] Liang J. H., Wei Q., Qiao C. F., Xia Z. Q, Ye G., Chen S. P., Chin. J. Chem., 2012, 30, 715
[32] Shimoni L. L., Glusker J. P., Bock C. W., Inorg. Chem., 1998, 37, 1853
[33] Hancock R. D., Reibenspies J. H., Maumela H., Inorg. Chem., 2004, 43, 2981
[34] Luckay R., Cukrowski I., Mashishi J., Reibenspies J. H., Bond A. H., Rogers R. D., Hancock R. D., J. Chem. Soc., Dalton Trans., 1997, 901
[35] Hua J. Y., Li S. S., Zhao J. A., Chen S. F., Hou H. W., Zhao H. P., J. Coord. Chem., 2012, 65, 1258
[36] Wang Z., Wei Q., Xie G., Yang Q., Chen S. P., Gao S. L., J. Coord. Chem., 2012, 65, 256
[37] Qiao C. F., Wei Q., Xia Z. Q., Liang J. H., Chen S. P., Chin. J. Chem., 2011, 29, 724
[38] Zhou H. P., Wang P., Zheng L. X., Geng W. Q., Yin J. H., Gan X. P., Xu G. Y., Wu J. Y., Tian Y. P., Kan Y. H., Tao X. T., Jiang M. H.. J. Phys. Chem. A, 2009, 113, 2584
[39] Simeon T. M., Ratner M. A., Schatz G. C., J. Phys. Chem. A, 2013, 117, 7918
[40] Xia Z. Q., Chen S. P., Wei Q., Qiao C. F., J. Solid State Chem., 2011, 184, 1777
[41] Vogler A., Kunkely H., Coord. Chem. Rev., 2006, 250, 1622
[42] Ballardini R., Varani G., Indelli M. T., Scandola F., Inorg. Chem., 1986, 25, 3858
[43] Kunkely H., Vogler A., Chem. Phys. Lett., 1999, 304, 187
[44] Djurovicht P. I., Watts R. J., Inorg. Chem., 1993, 32, 4681
[45] Valeur B., Molecular Fluorescence Principles and Applications, Wiley-VCH, Weinheim, 2002, 72
[46] Xu J. K., Sun X. C., Ju C. X., Yang L. R., Bi C. F., Sun M., J. Coord. Chem., 2013, 66, 2693
[47] Wang H. H., Gan Q., Wang X. J., Xue L., Liu S. H., Jiang H., Org. Lett., 2007, 9, 4995
[48] Zhao X. X., Ma J. P., Dong Y. B., Huang R. Q., Cryst. Growth Des., 2007, 7, 1058
[49] Zhao H., Chen J. M, Lin J. R., Wang W. X., J. Coord. Chem., 2011, 64, 2735