Three Ni(Ⅱ) Coordination Polymers with Various Architectures Based on Asymmetric Bis-pyridyl-amide and Polycarboxylates: Syntheses, Structures and Properties

doi:10.1007/s40242-016-6072-z

Abstract

Abstract:

Three different dimensional Ni(Ⅱ) coordination polymers,[Ni(3-pna)(HIP)(H₂O)₃]·H₂O(1),[Ni(3-pna)· (1,3,5-HBTC)](2) and [Ni₂(H₂O)(3-pna)₂(1,4-CHDC)₂]₄(3)(3-pna=3-pyridylnicotinamide, H₂HIP=5-hydroxyisoph-thalic acid, 1,3,5-H₃BTC=1,3,5-benzenetricarboxylic acid, 1,4-H₂CHDC=1,4-cyclohexanedicarboxylic acid), were synthesized under hydrothermal conditions and characterized by means of infrared spectra(IR), thermal gravimetric (TG) analyses, powder X-ray diffraction(PXRD) and single-crystal X-ray diffraction. Complex 1 has a structure of 1D single-stranded chain, which is further stretched by hydrogen-bond interactions to form a 2D supramolecular sheet. Complex 2 shows a 2D network, which is stretched to 3D supramolecular frameworks through hydrogen-bond interactions. Complex 3 reveals a 3D skeleton with a (3,3,6,6)-connected {3·7²}{3²·4}{3³·4²·5·7³·8⁵·9}{3³·4⁵·5²·7²·8²·9} topology. The effects of different polycarboxylates on the ultimate architectures of the complexes 1-3 were discussed. Furthermore, the fluorescent and photocatalytic properties of the title complexes were also investigated.

Key words: Crystal structure, Dipyridylamide, Polycarboxylate, Photoluminescence property, Photocatalytic property

WU Xiaomei, LIU Guocheng, WANG Xiuli, SHAO Jiyan, LIN Hongyan, WANG Xiang. Three Ni(Ⅱ) Coordination Polymers with Various Architectures Based on Asymmetric Bis-pyridyl-amide and Polycarboxylates: Syntheses, Structures and Properties[J]. Chemical Research in Chinese Universities, 2016, 32(5): 719-724.

References

[1] Wang C., Liu D. M., Lin W. B., J. Am. Chem. Soc., 2013, 135(36), 13222
[2] Wang B., Huang H. L., Lv X. L., Xie Y. B., Li M., Li J. R., Inorg. Chem., 2014, 53(17), 9254
[3] Zhao C., Wang N. X., Wang L., Huang H. L., Zhang R., Yang F., Xie Y. B., Ji S. L., Li J. R., Chem. Commun., 2014, 50(90), 13921
[4] Luo F., Che Y. X., Zheng J. M., Cryst. Growth. Des., 2008, 8(6), 2006
[5] Hanson K., Roskop L., Patel N., Griffe L., Djurovich P. I., Gordon M. S., Thompson M. E., Dalton Trans., 2012, 41(28), 8648
[6] Lu W. G., Wei Z. W., Gu Z. Y., Liu T. F., Park J., Tian J., Zhang M. W., Zhang Q., Gentle Ⅲ T., Bosch M., Zhou H. C., Chem. Soc. Rev., 2014, 43(16), 5561
[7] Santra A., Bharadwaj P. K., Cryst. Growth Des., 2014, 14(3), 1476
[8] Bai J., Zhou H. L., Liao P. Q., Zhang W. X., Chen X. M., Cryst. Eng. Comm., 2015, 17(24), 4462
[9] Yu Y. Y., Zhang L. J., Zhou Y. S., Zuhra Z., Dalton Trans., 2015, 44(10), 4601
[10] Han L. L., Hu T. P., Mei K., Guo Z. M., Yin C., Wang Y. X., Zheng J., Wang X. P., Sun D., Dalton Trans., 2015, 44(13), 6052
[11] Mu Y. J., Han G., Li Z., Liu X. T., Hou H. W., Fan Y. T., Cryst. Growth Des., 2012, 12(3), 1193
[12] Lee C. H., Huang H. Y., Liu Y. H., Luo T. T., Lee G. H., Peng S. M., Jiang J. C., Chao I., Lu K. L., Inorg. Chem., 2013, 52(7), 3962
[13] Pochodylo A. L., Wilson J. A., Uebler J. W., Qiblawi S. H., LaDuca R. L., Inorg. Chim. Acta, 2014, 423, 298
[14] Cheng J. J., Chang Y. T., Wu C. J., Hsu Y. F., Lin C. H., Proserpio D. M., Chen J. D., Cryst. Eng. Comm., 2012, 14(2), 537
[15] Sie M. J., Chang Y. J., Cheng P. W., Kuo P. T., Yeh C. W., Cheng C. F., Chen J. D., Wang J. C., Cryst. Eng. Comm, 2012, 14(17), 5505
[16] Du M., Li C. P., Liu C. S., Fang S. M., Coord. Chem. Rev., 2013, 257(7/8), 1282
[17] Kumar D. K. Jose D. A., Dastidar P., Das A., Langmuir, 2004, 20(24), 10413
[18] Sheldrick G. M., Acta Crystallogr. A, 2008, 64(1), 112
[19] Spek A. L., PLATON, A Multipurpose Crystallographic Tool, Utrecht University, Utrecht, 1998
[20] Hu J. S., Huang L. F., Yao X. Q., Qin L., Li Y. Z., Guo Z. J., Zheng H. G., Xue Z. L., Inorg. Chem., 2011, 50(6), 2404
[21] Wang X. L., Le M., Lin H. Y., Luan J., Liu G. C., Sui F. F., Chang Z. H., Inorg. Chem. Front., 2015, 2(4), 373
[22] Biswas R., Diaz C., Bauzá A., Barceló-Oliverc M., Frontera A., Ghosh A., Dalton Trans., 2014, 43(17), 6455
[23] Zhang M. D., Di C.M., Qin L., Yao X. Q., Li Y. Z., Guo Z. J., Zheng H. G., Cryst. Growth Des., 2012, 12(8), 3957
[24] Wang X. L., Mu B., Lin H. Y., Liu G. C., J. Organomet. Chem., 2011, 696(11/12), 2313
[25] Bellamy L. J., The Infrared Spectra of Complex Molecules, Wiley, New York, 1958
[26] Cui Y. J., Yue Y. F., Qian G. D., Chen B. L., Chem. Rev., 2012, 112(2), 1126
[27] Wang X. L., Luan J., Lu Q. L., Lin H. Y., Xu C., Liu G. C., J. Or-ganomet. Chem., 2013, 740, 17
[28] Gong Y., Wu T., Lin J. H., Cryst. Eng. Comm., 2012, 14(10), 3727
[29] Liu B., Yu Z. T., Yang J., Hua W., Liu Y. Y., Ma J. F., Inorg. Chem., 2011, 50(18), 8967
[30] Wang X. L., Gong C. H., Qu Y., Liu G. C., Zhang J. W., Chem. Res. Chinese Universities, 2014, 30(5), 709
[31] Liu L., Ding J., Huang C., Li M., Hou H. W., Fan Y. T., Cryst. Growth. Des., 2014, 14(6), 3035
[32] Lei X. W., Yue C. Y., Zhao J. Q., Han Y. F., Yang J. T., Meng R. R., Gao C. S., Ding H., Wang C. Y., Chen W. D., Hong M. C., Inorg. Chem., 2015, 54(22), 10593