A New Inorganic 2D Framework Based on Bi-bismuth-capping Keggin Polyoxometalate with Photodegradation and Selective Absorption of Organic Dyes

doi:10.1007/s40242-017-6475-5

Chemical Research in Chinese Universities ›› 2017, Vol. 33 ›› Issue (3): 333-338.doi: 10.1007/s40242-017-6475-5

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A New Inorganic 2D Framework Based on Bi-bismuth-capping Keggin Polyoxometalate with Photodegradation and Selective Absorption of Organic Dyes

SONG Jiangfeng¹, WANG Jun¹, ZHOU Ruisha¹, CUI Xiaobing²

1. Department of Chemistry, North University of China, Taiyuan 030051, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2016-11-28 Revised:2017-02-10 Online:2017-06-01 Published:2017-05-26
Contact: SONG Jiangfeng,E-mail:jfsong0129@nuc.edu.cn;CUI Xiaobing,E-mail:cuixb@mail.jlu.edu.cn E-mail:jfsong0129@nuc.edu.cn;cuixb@mail.jlu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.21201155), the Natural Science Young Scholars Foundation of Shanxi Province, China(Nos.2012021007-5, 2013021008-6), the Program for the Top Young Academic Leaders of Higher Learning Institutions of Shanxi Province, China, the 131 Talent Plan of Higher Learning Institutions of Shanxi Province, China and the Project of the Key Laboratory of Functional Inorganic Material Chemistry(Heilongjiang University) of the Ministry of Education of China.

Abstract

Abstract:

A new purely inorganic 2D framework, {PMo₁₂O₄₀Bi₂(H₂O)₂}·4H₂O(1), was synthesized under solvothermal condition and characterized by infrared(IR) spectroscopy, thermal gravimetric analysis, UV-Vis spectroscopy, powder X-ray diffraction and single-crystal X-ray diffraction. Structural analysis reveals that compound 1 consists of Keggin unit {PMo₁₂O₄₀} with two bismuth atoms capping two opposite pits, leading to the bi-bismuth-capping Keggin polyoxometalate. Compound 1 not only displays excellent photodegradation activity for methyl orange(MO), but also has a high absorption capacity for rhodamine B(RhB) and methylene blue(MB). Moreover, compound 1 is extremely stable and easily separated from the reaction system for reuse.

Key words: Bismuth, Polyoxometalate, Keggin, Absorption, Photocatalytic ability

SONG Jiangfeng, WANG Jun, ZHOU Ruisha, CUI Xiaobing. A New Inorganic 2D Framework Based on Bi-bismuth-capping Keggin Polyoxometalate with Photodegradation and Selective Absorption of Organic Dyes[J]. Chemical Research in Chinese Universities, 2017, 33(3): 333-338.

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A New Inorganic 2D Framework Based on Bi-bismuth-capping Keggin Polyoxometalate with Photodegradation and Selective Absorption of Organic Dyes

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