Construction of Two Chiral Bilayer Coordination Polymers Based on 2-(Pyridine-3-yl)-1H-4,5- imidazoledicarboxylate Ligand

doi:10.1007/s40242-013-2194-8

Chemical Research in Chinese Universities ›› 2013, Vol. 29 ›› Issue (1): 6-9.doi: 10.1007/s40242-013-2194-8

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Construction of Two Chiral Bilayer Coordination Polymers Based on 2-(Pyridine-3-yl)-1H-4,5- imidazoledicarboxylate Ligand

ZHOU Xiao-ying¹, JING Xue-min², XU Da¹, YAN Wei-wei³, LI Guang-hua¹, ZHANG Li-rong¹

1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China;
2. Faculty of Chemistry and Material Science, Langfang Teachers College, Langfang 065000, P. R. China;
3. College of Science, Changchun Institute of Technology, Changchun 130012, P. R. China

Received:2012-05-17 Revised:2012-06-23 Online:2013-02-01 Published:2013-01-23
Supported by:
Supported by the National Natural Science Foundation of China(No.20701015).

Abstract

Abstract:

Two novel isomorphic coordination polymers [Zn(HPyImDC)H₂O](1) and [Co(HPyImDC)H₂O](2) were synthesized from 2-(pyridine-3-yl)-1H-4,5-imidazoledicarboxylic acid (H₃PyImDC) under hydrothermal conditions. Both the compounds crystallized in P2₁2₁2₁ chiral space group, possessing left-hand helical chains and right-hand helical chains. Two types of helical chains connected with each other to form an interesting 2D bilayer structure which extended to a 3D supermolecular structure via the hydrogen-bonding interactions. Topology analysis shows that H₃PyImDC ligand and metal center can be regarded as 3-connected T-shaped nodes, thus leading to a (3,3)-connected network with vertex symbol of (8²·10).

Key words: Isomorphic, Helical chain, 2D Bilayer, Hydrogen-bonding, Fluorescence

ZHOU Xiao-ying, JING Xue-min, XU Da, YAN Wei-wei, LI Guang-hua, ZHANG Li-rong. Construction of Two Chiral Bilayer Coordination Polymers Based on 2-(Pyridine-3-yl)-1H-4,5- imidazoledicarboxylate Ligand[J]. Chemical Research in Chinese Universities, 2013, 29(1): 6-9.

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Construction of Two Chiral Bilayer Coordination Polymers Based on 2-(Pyridine-3-yl)-1H-4,5- imidazoledicarboxylate Ligand

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