Water-soluble Porphyrin as Temperature Sensor Based on Fluorescent Enhancement

doi:10.1007/s40242-014-3471-x

Chemical Research in Chinese Universities ›› 2014, Vol. 30 ›› Issue (3): 379-382.doi: 10.1007/s40242-014-3471-x

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Water-soluble Porphyrin as Temperature Sensor Based on Fluorescent Enhancement

FEI Qiang¹, WANG Chunyu¹, WANG Baojun¹, XU Hui¹, LI Guanghua², HUAN Yanfu¹, SHAN Hongyan¹, FENG Guodong^1,2

1. College of Chemistry, Jilin University, Changchun 130021, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2013-10-29 Revised:2013-12-26 Online:2014-06-01 Published:2014-05-24
Contact: FENG Guodong E-mail:fenggd@jlu.edu.cn
Supported by:
Supported by the State Major Project for Science and Technology Development, China(Nos.2011YQ14015001, 2013YQ47078102-3), the Science-Technology Development Project of Jilin Province of China(Nos.201105008, 20126018, 20130206014GX), the Basic Research Foundation of Jilin University, China(Nos.201103096, 201103102) and the Open Project for the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, China(No.2014-07).

Abstract

Abstract:

A novel water-soluble porphyrin[5,10,15,20-tetra(3-ethoxy-4-hydroxy-5-sulfonate)phenyl porphyrin, H₂TEHPPS] was designed and synthesized, which could be used as a potential fluorescence sensor to detect tempe- rature changes. The studies were performed in solution phase and the concentration of H₂TEHPPS was 2.0×10^-5 mol/L. The optical properties of H₂TEHPPS were investigated based on the UV and fluorescence spectra. The results show that the fluorescence intensity of H₂TEHPPS is directly proportional to temperature in the range of 293―353 K. So H₂TEHPPS can be used as a molecular temperature sensor in biomedical and other fields.

Key words: Water-soluble porphyrin, Enhanced fluorescence effect, Temperature, Sensor

FEI Qiang, WANG Chunyu, WANG Baojun, XU Hui, LI Guanghua, HUAN Yanfu, SHAN Hongyan, FENG Guodong. Water-soluble Porphyrin as Temperature Sensor Based on Fluorescent Enhancement[J]. Chemical Research in Chinese Universities, 2014, 30(3): 379-382.

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Water-soluble Porphyrin as Temperature Sensor Based on Fluorescent Enhancement

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