Chemical Research in Chinese Universities ›› 2012, Vol. 28 ›› Issue (5): 788-791 .

• Articles • Previous Articles     Next Articles

Hydrothermal Synthesis and Dielectric Characterization of a Double Perovskite Ba2FeSbO6

LI Min, YUAN Hong-ming, XU Wei, HAN Mei, YAO Lin-ran, YANG Ming, FENG Shou-hua   

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
  • Received:2011-08-08 Revised:2011-09-18 Online:2012-09-25 Published:2012-09-07
  • Supported by:
    Supported by the National Natural Science Foundation of China(Nos.90922034, 20771042).

Abstract: A double perovskite oxide Ba2FeSbO6 was hydrothermally synthesized and structurally characterized by X-ray diffraction. This solid compound shows a single phase and has a trigonal structure with space group R m and cell parameters of a=0.57261 nm and c=1.40244 nm. The dielectric constant and loss tangent of the solid measured in a frequency range from 100 Hz to 1 MHz at temperatures from 313 K to 513 K reveal a relaxation process of frequency dependence of the real part(ε') of dielectric constant and dielectric loss tand. The frequency dependence of electrical property led to the framework of conductivity and electric modulus formalisms. The scaling behavior of imaginary part of electric modulus suggests that the relaxation describes the single mechanism at various temperatures. The variation tendency of the alternating current impedance indicates the thermally activated conduction process follows Jonsche’s power law.

Key words: Double perovskite, Hydrothermal synthesis, Electrical property