Structural Characterization, Vibrational Studies and Electrical Properties of 2-Amino-3-benzyloxy Pyridinium Perchlorate

doi:10.1007/s40242-015-5206-z

Abstract

Abstract:

A title organic-inorganic hybrid material 2-amino-3-benzyloxy pyridinium perchlorate was synthesized by slow evaporation at room temperature using 2-amino-3-benzyloxypyridine as the structure-directing agent. The structure of the title compound was determined by means of single-crystal X-ray diffraction at 293 K. The results show that this compound crystallizes in the centrosymetric monoclinic system with a space group of P2₁/n and lattice parameters of a=0.7025(5) nm, b=1.2635(5) nm, c=1.5766(5) nm, Z=4 and V=1.3905(2) nm³. The crystal structure has been determined and refined to R₁=0.0367 and wR₂=0.1022 using 2326 independent reflections and can be described as a succession of organic and inorganic layers parallel to the bc plane. In this arrangement, hydrogen bonds and van der Waals interactions between different species play an important role in the two-dimensional(2D) network cohesion. This compound was also characterized by means of infrared spectroscopy, Raman spectroscopy and thermogravimetric analysis-differential thermal analysis(TG-DTA). Moreover, protonic conduction of this compound determined by an impedance analyzer has been studied in the temperature range of 303-373 K.

Key words: Organic-inorganic hybrid, Chemical synthesis, Infrared and Raman spectroscopy, Thermal analysis, Electrical property

SAMI Soukrata, MOHAMED Belhouchet, TAHAR Mhiri. Structural Characterization, Vibrational Studies and Electrical Properties of 2-Amino-3-benzyloxy Pyridinium Perchlorate[J]. Chemical Research in Chinese Universities, 2015, 31(5): 693-698.

References

[1] Pettinari C., Marchetti F., Pelli M., Cingolani A., Barba L., Cassetta A., J. Organomet. Chem., 1996, 515, 119
[2] Vasisht S. K., Kaur T. P., Kaushal J., Dixit S., J. Organomet. Chem., 1997, 540, 51
[3] Gielen M., Coord. Chem. Rev., 1996, 151, 41
[4] Rayes A., Ben N. C., Rzaigui M., Mater. Res. Bull., 2004, 39, 1113
[5] Kaabi K., Ben N. C., Rzaigui M., J. Phys. Chem. Solids, 2004, 65, 1759
[6] Kaabi K., Rayes A., Ben N. C., Rzaigui M., Lefebvre F., Mater. Res. Bull., 2003, 38, 741
[7] Akriche S. T., Rzaigui M., Al-Hokbany N., Mahfouz R. M., Acta Cryst. 2010, E66, o300
[8] Berrah F., Bouacida S., Anana H., Roisnel T., Acta Cryst., 2012, E68, o1601
[9] Sheldrick G. M., SADABS Bruker AXS Inc., Madison, Wisconsin, USA, 2002
[10] Sheldrick G. M., SHELXS-97, Program for the Solution of Crystal Structures, University of Göttingen, Göttingen, 1997
[11] Sheldrick G. M., SHELXL-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, 1997
[12] Brandenburg K., Crystal Impact, Diamond, Version 2.0 Bonn, Germany, 1998
[13] Farrugia L. J., J. Appl. Cryst., 1997, 30, 565
[14] Arunkumar A., Ramasamy P., J. Cryst. Growth, 2014, 388,124
[15] Czupinski O., Wojtas M., Pietraszko A., Jakubas R., Solid State Sci., 2007, 9, 108
[16] Boca M., Valigura D., Svoboda I., Fuess H., Linert W., Acta Cryst., 2000, C56, 838
[17] Kowalczyk I., Bartoszak-Adamska E., Jaskolski M., Dega-Szafran Z., Szafran M., J. Mol. Struct., 2010, 976, 119
[18] Anitha R., Athimoolam S., Gunasekaran M., Anitha K., J. Mol. Struct., 2014, 1076, 115
[19] Varga R. A., Rus A., Venter M. M., Pirjol T. N., Guran C., Acta Cryst., 2007, E63, o4317
[20] Shankar V. S., Siddheswaran R., Sankar R., Jayavel R., Murugakoothan P., Mater. Lett., 2009, 63, 363
[21] Marchewka M. K., Drozd M., Pietraszko A., Mater. Sci. Eng., 2003, B100, 225
[22] Janiak C., J. Chem. Soc., Dalton Trans., 2000, 21, 3885
[23] Janczak J., Perpetuo G. J., Solid State Sci., 2009, 11, 1576
[24] Kanagathara N., Marchewka M. K., Drozd M., Renganathan N. G., Gunasekaran S., Anbalagan G., Spectrochim Acta A, 2013, 112, 343
[25] Nakamoto K., Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A:Theory and Applications in Inorganic Chemistry, Wiley-Interscience, New York, 1986, 202
[26] Kessenti A., Belhouchet M., Sunol J. J., Abid Y., Mhiri T., J. Lumin., 2014, 149, 341
[27] Cyrac P. A., Vimalan M., Sagayaraj P., Madhavan J., Physica B, 2010, 405, 65
[28] Mariappan L., Kandasamy A., Rathnakumari M., Sureshkumar P., Optik, 2013, 124, 5707
[29] Labidi O., Roussel P., Huve M., Drache M., Conflant P., Wignacourt J. P., J. Solid State Chem., 2005, 178, 2247
[30] Liao W. Q., Zhou Q. Q., Li P. F., Zhang Y., Chinese Chem. Lett., 2014, 25, 723