Temperature-controlled Hydrothermal Synthesis of Copper(I or II) Coordination Polymers via a Variety of Copper Coordination Modes

Chemical Research in Chinese Universities ›› 2012, Vol. 28 ›› Issue (4): 581-584.

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Temperature-controlled Hydrothermal Synthesis of Copper(I or II) Coordination Polymers via a Variety of Copper Coordination Modes

QU Xue-jian, WANG Shuang, ZHANG Dao-jun, JING Xue-min, ZHANG Li-rong, LI Guang-hua, HUO Qi-sheng, LIU Yun-ling

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China

Received:2011-06-17 Revised:2011-08-13 Online:2012-07-25 Published:2012-07-25
Supported by:
Supported by the National Natural Science Foundation of China(Nos.20701015, 21071059, 20788101).

Abstract

Abstract: Two 1D coordination polymers Cu₂^I(C₆N₃H₄)₂(1) and Cu^II(C₆N₃H₄)₂·H₂O(2) based on benzotriazole(Bta) were hydrothermally synthesized by controlling the crystallization temperature. Single-crystal X-ray diffraction (XRD) analyses reveal that compound 1 is a 1D tubular structure constructed from two types of 1D chains {-Cu-N=N-N-}_n, where the Cu(I) ions adopt linear, triangular, and tetrahedral coordination modes to connect two types of Bta ligands via π-π interaction inside the tubular-like chain. For compound 2, the Cu(II) ions assume a quadrilateral coordination mode linking to the Bta ligands to give 1D straight chains, which stacks through π-π interactions to construct a 2D layer structure. Further characterizations including elemental analyses, infrared IR spectra, thermogravimetric(TG) analyses and luminescence properties have been done.

Key words: Hydrothermal synthesis, Coordination mode, Copper coordination polymer

QU Xue-jian, WANG Shuang, ZHANG Dao-jun, JING Xue-min, ZHANG Li-rong, LI Guang-hua, HUO Qi-sheng, LIU Yun-ling . Temperature-controlled Hydrothermal Synthesis of Copper(I or II) Coordination Polymers via a Variety of Copper Coordination Modes[J]. Chemical Research in Chinese Universities, 2012, 28(4): 581-584.

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Temperature-controlled Hydrothermal Synthesis of Copper(I or II) Coordination Polymers via a Variety of Copper Coordination Modes

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