Crystal Structure and Photoluminescence Properties of Two Barium(Ⅱ) MOFs

doi:10.1007/s40242-018-8054-9

Chemical Research in Chinese Universities ›› 2018, Vol. 34 ›› Issue (5): 700-704.doi: 10.1007/s40242-018-8054-9

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Crystal Structure and Photoluminescence Properties of Two Barium(Ⅱ) MOFs

LI Kai¹, HE Kunhuan², LI Quanwen², XIA Bin², WANG Qinglun², ZHANG Yinghui¹

1. Tianjin Key Laboratory of Metal and Molecule-based Material Chemistry, School of Materials Science and Engineering, Nankai University, Tianjin 300350, P. R. China;
2. Collaborative Innovation Center of Chemical Science and Engineering(Tianjin), College of Chemistry, Nankai University, Tianjin 300071, P. R. China

Received:2018-02-07 Revised:2018-06-03 Online:2018-10-01 Published:2018-06-19
Contact: WANG Qinglun,Email:wangql@nankai.edu.cn E-mail:wangql@nankai.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China(Nos.21771111, 21601092, 21371104), the-111‖ Project of China(No.B12015) and the Tianjin Natural Science Foundation, China(Nos.15JCZDJC38800, 16JCZDJC36900).

Abstract

Abstract: In this article, two Ba(Ⅱ) metal-organic frameworks(MOFs), {[Ba(BPS)(H₂O)₂]·H₂O}_n(1) and[Ba(BPS)(H₂O)₂]_n(2)(H₂BPS=4,4'-bibenzoic acid-2,2'-sulfone), were synthesized and characterized. X-Ray crystal structural analyses reveal that compounds 1 and 2 have different structures, which is probably related to different coordination modes of ligand in compounds 1 and 2. It is remarkable that compounds 1 and 2 both show excellent thermal stability. The solid-state emission spectra reveal that compounds 1 and 2 both present strong luminescence emission bands at room temperature.

Key words: Metal-organic framework, Coordination mode, Thermal stability, Solid-state emission spectrum, Barium (Ⅱ)

LI Kai, HE Kunhuan, LI Quanwen, XIA Bin, WANG Qinglun, ZHANG Yinghui. Crystal Structure and Photoluminescence Properties of Two Barium(Ⅱ) MOFs[J]. Chemical Research in Chinese Universities, 2018, 34(5): 700-704.

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Crystal Structure and Photoluminescence Properties of Two Barium(Ⅱ) MOFs

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