Hydrothermal Synthesis and Structure Characterization of Open-framework Cobalt-tungsten Phosphate [H3NCH2CH2NH3]3[Co3W4P4O28]

Chemical Research in Chinese Universities ›› 2010, Vol. 26 ›› Issue (6): 862-865.

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Hydrothermal Synthesis and Structure Characterization of Open-framework Cobalt-tungsten Phosphate [H3NCH2CH2NH3]3[Co3W4P4O28]

ZHANG Yan-lin¹, YU Hai-hui¹, ZHOU Yang¹, HOU Dian-hui¹ and KONG Li^2*

1. College of Chemical Engineering, Northeast Dianli University, Jilin 132012, P. R. China;
2. College of Chemical and Materials Engineering, Jilin Institute of Chemical Technology, Jilin 132012, P. R. China

Received:2010-03-12 Revised:2010-05-20 Online:2010-11-25 Published:2010-12-01
Contact: KONG Li E-mail:KL_0613@yahoo.com.cn
About author: KONG Li. E-mail: KL_0613@yahoo.com.cn
Supported by:
Supported by the National Natural Science Foundation of China(No.30800191).

Abstract

Abstract: A new three-dimensional open-framework cobalt(II)-tungsten(VI) phosphate, [H3NCH2CH2NH3]3?[Co3W4P4O28](1) has been synthesized from the reaction of CoCl2?6H2O, WO3, H3PO4, ethylenediamine and H2O. The title compound was fully characterized by infrared spectroscopy, elemental analysis, magnetic properties, thermogravimetric analysis, XPS and single-crystal X-ray diffraction. The compound crystallized in a tetragonal space group I4(1)/a with a=1.7118(4) nm, c=1.0773(2) nm, V =3.1568(11) nm3, Z =4.

Key words: Hydrothermal synthesis, Crystal structure, Polyoxometalate

ZHANG Yan-lin, YU Hai-hui, ZHOU Yang, HOU Dian-hui and KONG Li*. Hydrothermal Synthesis and Structure Characterization of Open-framework Cobalt-tungsten Phosphate [H3NCH2CH2NH3]3[Co3W4P4O28][J]. Chemical Research in Chinese Universities, 2010, 26(6): 862-865.

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Hydrothermal Synthesis and Structure Characterization of Open-framework Cobalt-tungsten Phosphate [H3NCH2CH2NH3]3[Co3W4P4O28]

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