Electrochemical Synthesis and Magnetic Studies of Ni-Fe-Co-Mn-Bi-Tm High Entropy Alloy Film

Chemical Research in Chinese Universities ›› 2010, Vol. 26 ›› Issue (4): 640-644.

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Electrochemical Synthesis and Magnetic Studies of Ni-Fe-Co-Mn-Bi-Tm High Entropy Alloy Film

YAO Chen-zhong^1,2, ZHANG Peng¹, TONG Ye-xiang^1*, XIA Dao-cheng² and MA Hui-xuan²

1. Key Laboratory of Bioinorganic and Synthetic Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, Institute of Optoelectronic and Functional Composite Materials, Sun Yat-Sen University, Guangzhou 510275, P. R. China;
2. Department of Applied Chemistry, Yuncheng University, Yuncheng 041000, P. R. China

Received:2009-10-29 Revised:2010-01-22 Online:2010-07-25 Published:2010-10-01
Contact: TONG Ye-xiang, E-mail: chedhx@mail.sysu.edu.cn
Supported by:
Supported by the National Natural Science Foundations of China(No.20873184), the Science and Technology Planning Project of Guangdong Province, China(No.2008B010600040) and the Foundation of Potentially Important Natural Science Research and Young Teacher Starting-up Research of Sun Yat-Sen University, China.

Abstract

Abstract: Amorphous Ni-Fe-Co-Mn-Bi-Tm high entropy alloy films were firstly prepared by potentiostatic electrodeposition. The results indicate that the six elements can be co-deposited in an organic system of DMF (N,N-dimethylformamide)-CH₃CN. The surface of the film is composed of compact and uniform particles with triangular cone shape and a particle size of 100—200 nm. A simple face-centered-cubic structure is identified by XRD patterns after the films were annealed under Ar atmosphere. The annealed alloy film shows soft magnetic properties and the magnetization decreases with Fe content decreasing.

Key words: High entropy alloy, Electrodeposition, Magnetic property, Heat treatment

YAO Chen-zhong, ZHANG Peng, TONG Ye-xiang*, XIA Dao-cheng and MA Hui-xuan. Electrochemical Synthesis and Magnetic Studies of Ni-Fe-Co-Mn-Bi-Tm High Entropy Alloy Film[J]. Chemical Research in Chinese Universities, 2010, 26(4): 640-644.

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Electrochemical Synthesis and Magnetic Studies of Ni-Fe-Co-Mn-Bi-Tm High Entropy Alloy Film

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