[Ce(H2 O)7 Al(OH)6 Mo6O18]·4H2 O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions

Abstract

Abstract: A new cerium polyoxomolybdate {[Ce(H₂O)₇Al(OH)₆Mo₆O₁₈]·4H₂O} (compound 1) was synthesized and characterized by X-ray diffraction analysis, elemental analysis, TG analysis and IR spectrometry.Compound 1 exhibits a zigzag chain-like structure, which is constructed from an Anderson type anion and rare earth metal, Ce (Ⅲ).These 1-D chains are further extended into a 3-D network by the aid of multipoint hydrogen-bonding interactions.

Key words: One-pot reaction, Zigzag chain-like polymer, Rare earth metal, Polyoxometalate

JIN Hua, QI Yan-fei, QIN Chao, WANG Xin-long, WANG En-bo, XU Lin. [Ce(H₂ O)₇ Al(OH)₆ Mo₆O₁₈]·4H₂ O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions[J]. Chemical Research in Chinese Universities, 2005, 21(6): 637-640.

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[Ce(H₂ O)₇ Al(OH)₆ Mo₆O₁₈]·4H₂ O: A New One-dimensional Zigzag Chainlike Structure of Anderson Cluster Linked by Cerium Ions

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