Synthesis of Five-coordinated Anionic Tin(Ⅳ) Complexes and Crystal Structure of [(I-Pr)2NH2][PhSn(μ2-SCH2COO)2]

Chemical Research in Chinese Universities ›› 2004, Vol. 20 ›› Issue (3): 274-276.

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Synthesis of Five-coordinated Anionic Tin(Ⅳ) Complexes and Crystal Structure of [(I-Pr)₂NH₂][PhSn(μ²-SCH₂COO)₂]

ZHONG Gui-yun, SONG Hai-bin, XIE Qing-lan, SUN Li-juan

Institute of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, P. R. China

Received:2003-01-02 Online:2004-06-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20372035).

Abstract

Abstract: Four new five-coordinated anionic tin(Ⅳ) complexes with a form of [R_nNH_4-n][PhSn(μ²-SCH₂COO)₂] were synthesized via the reaction of mercaptoacetic acid with phenyltin trichloride in the presence of different organic bases and characterized by means of IR, ¹H NMR and MS spectroscopies. The crystal structure of [(i-Pr)₂NH₂][PhSn(μ²-SCH₂COO)₂] was determined by X-ray diffraction. In the crystal structure, the tin atom is five-coordinated and exists in trigonal bipyramid geometry with cell parameters a=1.1766(11) nm, b=1.3144(14) nm, c=1.3336(15) nm, β=90° and Z=4.

Key words: Five-coordinated tin(Ⅳ) complex, Ionic organotin, Crystal structure

ZHONG Gui-yun, SONG Hai-bin, XIE Qing-lan, SUN Li-juan. Synthesis of Five-coordinated Anionic Tin(Ⅳ) Complexes and Crystal Structure of [(I-Pr)₂NH₂][PhSn(μ²-SCH₂COO)₂][J]. Chemical Research in Chinese Universities, 2004, 20(3): 274-276.

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Synthesis of Five-coordinated Anionic Tin(Ⅳ) Complexes and Crystal Structure of [(I-Pr)₂NH₂][PhSn(μ²-SCH₂COO)₂]

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