Hydrothermal Synthesis and Characterization of [V16O38(Cl)][Cu(enMe)2]3.5·2H2O Containing {V16O38} Cluster

Chemical Research in Chinese Universities ›› 2004, Vol. 20 ›› Issue (3): 266-269.

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Hydrothermal Synthesis and Characterization of [V₁₆O₃₈(Cl)][Cu(enMe)₂]_3.5·2H₂O Containing {V₁₆O₃₈} Cluster

CUI Xiao-bing¹, ZHENG Shou-tian¹, SUN Yan-qiong¹, YANG Guo-yu^1,2

1. Coordination and Hydrothermal Chemistry Group, State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, P. R. China;
2. State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, P. R. China

Received:2003-04-02 Online:2004-06-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.20271050 and 20171045), the Talents Program of Chinese Academy of Sciences and the Natural Science Foundation of Fujian Province(No.E0210029).

Abstract

Abstract: Compound [V₁₆O₃₈(Cl)][Cu(enMe)₂]_3.5·2H₂O(1) has been hydrothermally synthesized and characterized by means of single-crystal X-ray diffraction, elemental analysis, IR, EPR and TGA analysis. The X-ray crystallography shows that compound 1 contains a new {V₁₆O₃₈} cluster shell, which is connected by [Cu(enMe)₂]²⁺ coordination fragments into a 3-D framework. The compound crystallized in a monoclinic system with space group P2(1)/n, M=2235.82, a=1.26076(3) nm, b=2.55802(6) nm, c=2.14742(4) nm, β=90.7380(10)°, V=6.9250(3) nm³, Z=4, F(000)=4418, D_c=2.145 g·cm^-3, μ=3.227 mm^-1,(Δ/σ)=0.000, S=1.066.

Key words: Hydrothermal synthesis, Polyoxovanadate, Crystal structure, Three-dimensional structure, Open-framework

CUI Xiao-bing, ZHENG Shou-tian, SUN Yan-qiong, YANG Guo-yu. Hydrothermal Synthesis and Characterization of [V₁₆O₃₈(Cl)][Cu(enMe)₂]_3.5·2H₂O Containing {V₁₆O₃₈} Cluster[J]. Chemical Research in Chinese Universities, 2004, 20(3): 266-269.

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Hydrothermal Synthesis and Characterization of [V₁₆O₃₈(Cl)][Cu(enMe)₂]_3.5·2H₂O Containing {V₁₆O₃₈} Cluster

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