Synthesis and Characterizaion of a New Inorganic-organic Sulfate Compound——Crystal Structure of [Ni(H2O)6][H2N(C2H4)2NH2](SO4)2

Chemical Research in Chinese Universities ›› 2004, Vol. 20 ›› Issue (1): 1-5.

• Articles • Next Articles

Synthesis and Characterizaion of a New Inorganic-organic Sulfate Compound——Crystal Structure of [Ni(H₂O)₆][H₂N(C₂H₄)₂NH₂](SO₄)₂

MENG He, XING Yan, FU Yun-long, SHI Zhan, PANG Wen-qin

State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China

Received:2002-12-30 Online:2004-02-24 Published:2011-08-06
Supported by:
Supportted by the State Basic Research Project of China(No.G200077507), the National Natural Science Foundation of China(No.20141004), and the State Key Laboratory of Inorganic Synthesis and Preparative Chemistry of Jilin University.

Abstract

Abstract: [Ni(H₂O)₆][H₂N(C₂H₄)₂NH₂](SO₄)₂ is an inorganic-organic compound with a new open framework synthesized by hydrothermal method, and characterized by means of single-crystal diffraction and spectroscopic data. The compound crystallized in a monoclinic space group P2₁/n with a=1.29089(2) nm, b=1.06301(3) nm, c=1.33202(4) nm, β=114.0870(10)°, V=1.67127(8) nm³, Z=4, and was solved by using the direct method and the least-squares refinement converged at R=0.0214[I>2σ(I)]. The structure consists of isolated Ni(H₂O)₆ octahedra and SO₄ tetrahedra, with both of them hydrogen-bonded to piperazine cations.

Key words: Inorganic-organic compound, Crystal structure, Nickel sulfate

MENG He, XING Yan, FU Yun-long, SHI Zhan, PANG Wen-qin. Synthesis and Characterizaion of a New Inorganic-organic Sulfate Compound——Crystal Structure of [Ni(H₂O)₆][H₂N(C₂H₄)₂NH₂](SO₄)₂[J]. Chemical Research in Chinese Universities, 2004, 20(1): 1-5.

[1]	HUA Chen, YI Pin, LIU Wencong, WANG Mengfan, NIU Zheng, LANG Jianping. Coordination Polymers with Bipyridyl Diene and Triene Ligands: Synthesis, Structures and Luminescent Properties [J]. Chemical Research in Chinese Universities, 2022, 38(1): 209-216.
[2]	ZHANG Wenqi, LIN Zhengguo, CHI Yingnan, HONG Jie, YAN Li, HU Changwen. Assembly of Three Scandium-containing Heteropolytungstates Based on a Building-block Synthetic Strategy [J]. Chemical Research in Chinese Universities, 2020, 36(6): 1161-1167.
[3]	ZANG Jiahe, ZHANG Qing'an, SUN Dalin. Crystal Structures and Electrochemical Properties of R_1.5Ca_1.5MgNi₁₄(R=Nd, Gd and Er) Hydrogen Storage Alloys [J]. Chemical Research in Chinese Universities, 2019, 35(6): 1040-1045.
[4]	WANG Dongmei, LOU Shengjun, YING Yiting, GUO Zhiqi, WANG Lijun. Assembly of Two Isostructural Metal-organic Frameworks Based on Hetero-N,O Donor Ligand for Detecting Nitro Explosives [J]. Chemical Research in Chinese Universities, 2019, 35(5): 762-766.
[5]	MA Xiao, WANG Xiaohong, SHANG Fan, DING Zimei, HANG Xiaojing, HUANG Jie. Studies on 3-Amino-4-(1H-tetrazol-5-yl)-furazan: Crystal Structure, Thermal Behavior and Energetic Performance [J]. Chemical Research in Chinese Universities, 2019, 35(5): 848-853.
[6]	ZHONG Liangxuan, LIU Mingyue, ZHANG Bowei, SUN Yaqiu, XU Yanyan. Syntheses, Crystal Structures, Magnetic and Near-infrared Luminescence Properties of 3d-4f Coordination Polymers Cu₂Pr₂, Cu₂Eu₂ and Cu₄Tb₂ [J]. Chemical Research in Chinese Universities, 2019, 35(4): 693-699.
[7]	YU Yanzhao, CAO Jiapeng, XU Yan. Two Pentavanadate-based Organic-inorganic Materials with Third-order NLO Properties [J]. Chemical Research in Chinese Universities, 2019, 35(1): 1-4.
[8]	DING Zimei, CAO Wenli, ZHENG Hui, HUANG Jie, XU Kangzhen, SONG Jirong. Synthesis, Structure Characteristic and Thermal Behavior of Two New Metal-organic Azo-triazole Compounds: [Zn(phen)₃]·ZTO·6H₂O and[Cu(phen)₃]·ZTO·6H₂O [J]. Chemical Research in Chinese Universities, 2018, 34(6): 1009-1013.
[9]	CHEN Xiang, ZENG Tian, ZHANG Cong, GUO Zhaoqi, LI Shuailei, MAI Tao, GAO Rong, MA Haixia. Crystal Structures, Thermal Behavior Analysis and Thermal Safety of Two Energetic Salts of Hydrazinyl-1,2,4,5-tetrazine with 3,5-Dinitrosalicylic Acid [J]. Chemical Research in Chinese Universities, 2018, 34(6): 959-964.
[10]	LIU Chao, LIU Yijie, ZHANG Lili, JIANG Kun, ZHANG Li. Two Coordination Compounds Bearing Bis(2-dimethylaminoethyl) Ether: Syntheses, Crystal Structures and Catalytic Application to the Henry Reaction [J]. Chemical Research in Chinese Universities, 2018, 34(3): 358-362.
[11]	WANG Jingyang, ZHANG Meng, XU Xiaodong, FENG Jing, WANG Yanli, ZHANG Milin, HAN Wei, CHEN Yitung, TIAN Guoxin. Synthesis and Characterization of [Cu(N-MeIm)₄(BF₄)₂] in Ionic Liquid [J]. Chemical Research in Chinese Universities, 2018, 34(1): 8-12.
[12]	ZHOU Jinhua, LI Jingjing, LI Jie, REN Guoyu, REN Yinghui, MA Haixia. Structure and Enhanced Antifungal Activity of a Divalent Cobalt(II) Complex with Hexaconazole [J]. Chemical Research in Chinese Universities, 2017, 33(6): 864-868.
[13]	WANG Xiang, LIN Lin, LIN Hongyan, LIU Guocheng. Syntheses, Structure and Properties of a 3d-4d/2-ptz Heterometallic Organic Chain-modified POM-based Framework [J]. Chemical Research in Chinese Universities, 2017, 33(1): 7-11.
[14]	HE Yuanchun, GUO Jiao, XU Na, YU Yang. Assembly of Five Coordination Polymers Based on 5,11,17,23-Tetra-tert-butyl-25-(carboxymethoxy)-calix[4]arene Ligand [J]. Chemical Research in Chinese Universities, 2017, 33(1): 44-48.
[15]	YAN Xia, ZHANG Jianxin. Copper(II) Complexes Based on 4'-R-Terpyridine: Synthesis, Structures, and Photocatalytic Properties [J]. Chemical Research in Chinese Universities, 2017, 33(1): 1-6.

Synthesis and Characterizaion of a New Inorganic-organic Sulfate Compound——Crystal Structure of [Ni(H₂O)₆][H₂N(C₂H₄)₂NH₂](SO₄)₂

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments