Syntheses of Novel Asymmetric Cyclopentanone Dyes and Measurement of Two-photon Absorption Cross-section

Chemical Research in Chinese Universities ›› 2003, Vol. 19 ›› Issue (4): 470-473.

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Syntheses of Novel Asymmetric Cyclopentanone Dyes and Measurement of Two-photon Absorption Cross-section

WANG Tao¹, WU Fei-peng¹, SHI Meng-quan¹, GUO Heng-chang², WU Cheng-yin², JIANG Hong-bing², GONG Qi-huang²

1. Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101, P. R. China;
2. State Key Laboratory for Mesoscopic Physics, Department of Physics, Peking University, Beijing 100871, P. R. China

Received:2002-11-06 Online:2003-12-24 Published:2011-08-06
Supported by:
Supported by the National Natural Science Foundation of China(No.50173031) and Ministry of Science and Technology of China(No.G1999033004).

Abstract

Abstract: A simple synthesis route with a high yield of novel asymmetric cyclopentanone dyes 3a-3e and their highly two-photon up-converted fluorescences are reported. The dyes have good solubilities in most of ordinary solvents, a wide UV absorption wavelength range from 380-540 nm, and high fluorescence quantum yields. The two-photon absorption cross-sections of dyes 3a-3e were measured in chloroform by a two-photon induced fluorescence method. All of these properties of the new dyes make them suitable for being used as two-photon fluorescent probes.

Key words: Two-photon, Up-converted fluorescence, Cyclopentanone, Fluorescent probe

WANG Tao, WU Fei-peng, SHI Meng-quan, GUO Heng-chang, WU Cheng-yin, JIANG Hong-bing, GONG Qi-huang. Syntheses of Novel Asymmetric Cyclopentanone Dyes and Measurement of Two-photon Absorption Cross-section[J]. Chemical Research in Chinese Universities, 2003, 19(4): 470-473.

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Syntheses of Novel Asymmetric Cyclopentanone Dyes and Measurement of Two-photon Absorption Cross-section

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