A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg2+

doi:10.1007/s40242-016-6001-1

Chemical Research in Chinese Universities ›› 2016, Vol. 32 ›› Issue (5): 742-745.doi: 10.1007/s40242-016-6001-1

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A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺

CHEN Jiayi¹, SHU Wei¹, WANG Enju²

1. School of Chemistry and Chemical Engineering, Hainan Normal University, Haikou 571158, P. R. China;
2. Key Laboratory of Tropical Medicinal Plant Chemistry, Ministry of Education, Hainan Normal University, Haikou 571158, P. R. China

Received:2016-01-04 Revised:2016-05-05 Online:2016-10-01 Published:2016-06-27
Contact: WANG Enju E-mail:enjuwang@163.com
Supported by:
Supported by the National Natural Science Foundation of China(No.21162010).

Abstract

Abstract:

A new fluorescent probe for the detection of Hg²⁺ was designed and synthesized via attaching N-methylisatin to rhodamine B hydrazide through an imine linkage. In an ethanol-Tris buffer medium, the addition of Hg²⁺ caused a strong orange fluorescence and a visual color change from colorless to pink. Other coexisting metal ions did not interfere with the detection of Hg²⁺. The research on the detection of Hg²⁺ in natural water suggested the possibility of practical applications in environment monitoring. Based on ESI-MS analysis, the Hg²⁺-sensing mechanism was proposed.

Key words: Fluorescent probe, Isatin, Rhodamine B, Mercury(Ⅱ) ion

CHEN Jiayi, SHU Wei, WANG Enju. A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺[J]. Chemical Research in Chinese Universities, 2016, 32(5): 742-745.

References

[1] Bolger P. M., Schwetz B. A., N. Engl. J. Med., 2002, 347, 1735
[2] Carter K. P., Young A. M., Palmer A. E., Chem. Rev., 2014, 114, 4564
[3] Kim H. N., Ren W. X., Kim J. S., Yoon J., Chem. Soc. Rev., 2012, 41, 3210
[4] Wang C., Zhang D., Huang X., Ding P., Wang Z., Zhao Y., Ye Y., Sensor. Actuat. B:Chem., 2014, 198, 33
[5] Qian X., Xu Z., Chem. Soc. Rev., 2015, 44, 4487
[6] Selid P. D., Xu H., Collins E. M., Face-Collins M. S., Zhao J. X., Sensors, 2009, 9, 5446
[7] Chen X., Pradhan T., Wang F., Kim J. S., Yoon J., Chem. Rev., 2012, 112, 1910
[8] Kim H. N., Lee M. H., Kim H. J., Kim J. S., Yoon J., Chem. Soc. Rev., 2008, 37, 1465
[9] Yuan L., Lin W., Zhang K., Zhu S., Acc. Chem. Res., 2013, 46, 1462
[10] Zhou X., Yan W., Zhao T., Tian Z., Wu X., Tetrahedron, 2013, 69, 9535
[11] Chen X., Meng X., Wang S., Cai Y., Wu Y., Feng Y., Zhu M., Guo Q., Dalton Trans., 2013, 42, 14819
[12] Saha S., Mahato P., Reddy G. U., Suresh E., Chakrabarty A., Baidya M., Ghosh S. K., Das A., Inorg. Chem., 2012, 51, 336
[13] Wang M., Yan F., Zou Y., Chen L., Yang N., Zhou X., Sensor Actuat. B:Chem., 2014, 192, 512
[14] Hu J., Hu Z., Cui Y., Zhang X., Gao H. W., Uvdal K., Sensor Actuat. B:Chem., 2014, 203, 452
[15] Fu Y., Tian Q. F., Guo Y. Q., Zang S. Q., Inorg. Chem. Acta, 2014, 419, 141
[16] Saleem M., Lee K. H., J. Lumin., 2014, 145, 843
[17] Yin J., Ma X., Wei G., Wei D., Du Y., Sensor Actuat. B:Chem., 2013, 177, 213
[18] Xiang Y., Tong A., Jin P., Ju Y., Org. Lett., 2006, 8, 2863
[19] Huang J., Xu Y., Qian X., Dalton Trans., 2014, 43, 5983
[20] Sheng H., Meng X., Ye W., Feng Y., Sheng H., Wang X., Guo Q. X., Sensor Actuat. B:Chem., 2014, 195, 534
[21] Piao J., Lv J., Zhou X., Zhao T., Wu X., Spectrochim. Acta Part A, 2014, 128, 475
[22] Liu D., Pang T., Ma K., Jiang W., Bao X., RSC Adv., 2014, 4, 2563
[23] Shim S. Y., Tae J. S., Bull. Korean Chem. Soc., 2011, 32, 2928
[24] Li Z., Hu Q., Li C., Dou J., Cao J., Chen W., Zhu Q., Tetrahedron Lett., 2014, 55, 1258
[25] Huo F. J, Su J., Sun Y. Q, Yin C. X., Tong H. B., Nie Z. X., Dyes Pigments, 2010, 86, 50
[26] Kwon J. Y., Jang Y. J., Lee Y. J., Kim K. M., Seo M. S., Nam W., Yoon J., J. Am. Chem. Soc., 2005, 127, 10107
[27] Yang X. F., Guo X. Q., Zhao Y. B., Talanta, 2002, 57, 883
[28] Goswami S., Paul S., Manna A., RSC Adv., 2013, 3, 10639

A Fluorescent and Colorimetric Probe Based on Isatin-appended Rhodamine for the Detection of Hg²⁺

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